stilbenes and carbene
stilbenes has been researched along with carbene* in 4 studies
Other Studies
4 other study(ies) available for stilbenes and carbene
| Article | Year |
|---|---|
Ruthenium-Catalyzed (
The metal-catalyzed ( Topics: Alkynes; Antineoplastic Agents, Phytogenic; Boron; Isomerism; Methane; Molecular Structure; Naphthalenes; Ruthenium; Stilbenes | 2019 |
N-Heterocyclic Carbene-Modified Au-Pd Alloy Nanoparticles and Their Application as Biomimetic and Heterogeneous Catalysts.
The preparation of water-soluble, N-heterocyclic-carbene-stabilized Au-Pd alloy nanoparticles by a straightforward ligand exchange process is presented. Extensive analysis revealed excellent size retention and stability over years in water. The alloy nanoparticles were applied as biomimetic catalysts for aerobic oxidation of d-glucose, for which monometallic Au and Pd nanoparticles showed no or negligible activity. The alloy nanoparticles were further applied as titania-supported heterogeneous catalysts for the mild hydrogenation of nitroarenes and the semihydrogenation of 1,2-diphenylacetylene with a solvent-dependent selectivity switch between E- and Z-stilbene. Topics: Alloys; Catalysis; Glucose; Gold; Hydrogenation; Methane; Nanoparticles; Oxidation-Reduction; Palladium; Particle Size; Stereoisomerism; Stilbenes; Titanium | 2018 |
Dehydrative fragmentation of 5-hydroxyalkyl-1H-tetrazoles: a mild route to alkylidenecarbenes.
The development of a mild, base-free method for the generation of alkylidenecarbenes is reported. Treatment of 5-hydroxyalkyl-1H-tetrazoles with carbodiimides generates products arising from the 1,2-rearrangement or [1,5]-C-H bond insertion of a putative alkylidenecarbene. Formation of this divalent intermediate is proposed to occur by way of a tetraazafulvene, which undergoes extrusion of 2 mol of dinitrogen. Details of this methodology, its application to the synthesis of combretastatin A-4, and an improved route to 5-hydroxyalkyl-1H-tetrazoles are described. Topics: Combinatorial Chemistry Techniques; Methane; Molecular Structure; Stilbenes; Tetrazoles | 2012 |
An efficient route to tetrahydronaphthols via addition of ortho-lithiated stilbene oxides to alpha,beta-unsaturated fischer carbene Complexes.
[reaction: see text] A stereoselective/stereospecific synthesis of polysubstituted tetrahydronaphthols based on the Michael addition of ortho-lithiated stilbene oxides to alpha,beta-unsaturated Fischer carbene complexes followed by an unusual cyclization of the corresponding intermediate in a 6-endo-tet mode is described. Topics: Cyclization; Hydrocarbons; Lithium; Macromolecular Substances; Methane; Molecular Structure; Naphthols; Stereoisomerism; Stilbenes | 2005 |