stevioside has been researched along with octane* in 1 studies
1 other study(ies) available for stevioside and octane
| Article | Year |
|---|---|
Synthesis of skeletally diverse and stereochemically complex library templates derived from isosteviol and steviol.
We have applied a diversity-oriented approach for the synthesis of skeletally diverse and stereochemically complex templates for small-molecule library production by performing Beckmann rearrangement and Beckmann fragmentation reactions on the bicyclo[3.2.1]octane rings of steviol and isosteviol, aglycones derived from the diterpene natural product stevioside. The optimization of these two reaction pathways is presented along with the successful application of a photo-Beckmann rearrangement. This work also led to the discovery of cyano-Prins-type and Thorpe-Ziegler-type cyclization reactions. Topics: Biological Products; Combinatorial Chemistry Techniques; Cyclization; Diterpenes, Kaurane; Glucosides; Nuclear Magnetic Resonance, Biomolecular; Octanes | 2013 |