boron and acetophenone

boron has been researched along with acetophenone* in 1 studies

Other Studies

1 other study(ies) available for boron and acetophenone

Article	Year
Asymmetric allylboration reactions with Soderquist's chiral 10-substituted-9-borabicyclo[3.3.2]decanes: a theoretical study. The Journal of organic chemistry, 2009, May-01, Volume: 74, Issue:9 Chiral B-allyl-10-substituted-9-borabicyclo[3.3.2]decanes are highly efficient reagents for the enantioselective allylboration of adehydes and ketones. In this study, we use DFT calculations to rationalize the experimentally observed reactivity and selectivity. Calculations correctly reproduced the experimental reactivity trends and enantioselectivities. Our results suggest that the origin of the facial selectivity relies strongly on steric effects. Topics: Acetophenones; Aldehydes; Alkanes; Boron; Quantum Theory; Stereoisomerism	2009

Article

Year

Asymmetric allylboration reactions with Soderquist's chiral 10-substituted-9-borabicyclo[3.3.2]decanes: a theoretical study.

The Journal of organic chemistry, 2009, May-01, Volume: 74, Issue:9

Chiral B-allyl-10-substituted-9-borabicyclo[3.3.2]decanes are highly efficient reagents for the enantioselective allylboration of adehydes and ketones. In this study, we use DFT calculations to rationalize the experimentally observed reactivity and selectivity. Calculations correctly reproduced the experimental reactivity trends and enantioselectivities. Our results suggest that the origin of the facial selectivity relies strongly on steric effects.

Topics: Acetophenones; Aldehydes; Alkanes; Boron; Quantum Theory; Stereoisomerism

2009