boron and acetophenone
boron has been researched along with acetophenone* in 1 studies
Other Studies
1 other study(ies) available for boron and acetophenone
| Article | Year |
|---|---|
Asymmetric allylboration reactions with Soderquist's chiral 10-substituted-9-borabicyclo[3.3.2]decanes: a theoretical study.
Chiral B-allyl-10-substituted-9-borabicyclo[3.3.2]decanes are highly efficient reagents for the enantioselective allylboration of adehydes and ketones. In this study, we use DFT calculations to rationalize the experimentally observed reactivity and selectivity. Calculations correctly reproduced the experimental reactivity trends and enantioselectivities. Our results suggest that the origin of the facial selectivity relies strongly on steric effects. Topics: Acetophenones; Aldehydes; Alkanes; Boron; Quantum Theory; Stereoisomerism | 2009 |