methyltrioxorhenium and Dehydration

methyltrioxorhenium has been researched along with Dehydration* in 1 studies

Other Studies

1 other study(ies) available for methyltrioxorhenium and Dehydration

Article	Year
Mechanistic insights into the rhenium-catalyzed alcohol-to-olefin dehydration reaction. Chemistry (Weinheim an der Bergstrasse, Germany), 2013, Sep-23, Volume: 19, Issue:39 Rhenium-based complexes are powerful catalysts for the dehydration of various alcohols to the corresponding olefins. Here, we report on both experimental and theoretical (DFT) studies into the mechanism of the rhenium-catalyzed dehydration of alcohols to olefins in general, and the methyltrioxorhenium-catalyzed dehydration of 1-phenylethanol to styrene in particular. The experimental and theoretical studies are in good agreement, both showing the involvement of several proton transfers, and of a carbenium ion intermediate in the catalytic cycle. Topics: Alcohols; Alkenes; Catalysis; Coordination Complexes; Dehydration; Organometallic Compounds; Protons; Quantum Theory; Rhenium	2013

Article

Year

Mechanistic insights into the rhenium-catalyzed alcohol-to-olefin dehydration reaction.

Chemistry (Weinheim an der Bergstrasse, Germany), 2013, Sep-23, Volume: 19, Issue:39

Rhenium-based complexes are powerful catalysts for the dehydration of various alcohols to the corresponding olefins. Here, we report on both experimental and theoretical (DFT) studies into the mechanism of the rhenium-catalyzed dehydration of alcohols to olefins in general, and the methyltrioxorhenium-catalyzed dehydration of 1-phenylethanol to styrene in particular. The experimental and theoretical studies are in good agreement, both showing the involvement of several proton transfers, and of a carbenium ion intermediate in the catalytic cycle.

Topics: Alcohols; Alkenes; Catalysis; Coordination Complexes; Dehydration; Organometallic Compounds; Protons; Quantum Theory; Rhenium

2013