zn(ii)-phthalocyanine and stannic-oxide

zn(ii)-phthalocyanine has been researched along with stannic-oxide* in 1 studies

Other Studies

1 other study(ies) available for zn(ii)-phthalocyanine and stannic-oxide

Article	Year
Photosensitization of SnO(2)/ZnO semiconductors with zinc-phthalocyanine. Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 2009, Volume: 72, Issue:3 Zinc-phthalocyanine with tyrosine substituent (ZnPcTyro) was attached to different nanocrystalline semiconductors (SnO(2) and ZnO) via carboxylic acid group, the interaction of zinc-phthalocyanine with colloidal ZnO and SnO(2) was studied by absorption and fluorescence spectroscopy. The apparent association constant for the association between ZnPcTyro and SnO(2)/ZnO is ranged from (3.7+/-0.2)x10(5)M(-1) to (6.7+/-0.2)x10(4)M(-1) with a degree of association ranged from 85% to 95%. The presence of the tyrosine group in ZnPcTyro affects solubility of the dye and affects the aggregation behavior of the dye. Anchoring of the dye complex to the nanocrystalline semiconductors enables ultrafast injection of electrons from the excited state into the conduction band of semiconductors. Maximum incident photon-to-current conversion of 0.84-1% at 600 nm and photon-to-current conversion efficiency of around 37% and 43% was obtained for ZnPc-sensitized-SnO(2) and ZnPc-sensitized-ZnO. Topics: Colloids; Coloring Agents; Hydrogen-Ion Concentration; Indoles; Isoindoles; Models, Chemical; Molecular Structure; Nanoparticles; Organometallic Compounds; Particle Size; Photochemical Processes; Semiconductors; Solubility; Spectrometry, Fluorescence; Tin Compounds; Zinc Compounds; Zinc Oxide	2009

Article

Year

Photosensitization of SnO(2)/ZnO semiconductors with zinc-phthalocyanine.

Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 2009, Volume: 72, Issue:3

Zinc-phthalocyanine with tyrosine substituent (ZnPcTyro) was attached to different nanocrystalline semiconductors (SnO(2) and ZnO) via carboxylic acid group, the interaction of zinc-phthalocyanine with colloidal ZnO and SnO(2) was studied by absorption and fluorescence spectroscopy. The apparent association constant for the association between ZnPcTyro and SnO(2)/ZnO is ranged from (3.7+/-0.2)x10(5)M(-1) to (6.7+/-0.2)x10(4)M(-1) with a degree of association ranged from 85% to 95%. The presence of the tyrosine group in ZnPcTyro affects solubility of the dye and affects the aggregation behavior of the dye. Anchoring of the dye complex to the nanocrystalline semiconductors enables ultrafast injection of electrons from the excited state into the conduction band of semiconductors. Maximum incident photon-to-current conversion of 0.84-1% at 600 nm and photon-to-current conversion efficiency of around 37% and 43% was obtained for ZnPc-sensitized-SnO(2) and ZnPc-sensitized-ZnO.

Topics: Colloids; Coloring Agents; Hydrogen-Ion Concentration; Indoles; Isoindoles; Models, Chemical; Molecular Structure; Nanoparticles; Organometallic Compounds; Particle Size; Photochemical Processes; Semiconductors; Solubility; Spectrometry, Fluorescence; Tin Compounds; Zinc Compounds; Zinc Oxide

2009