yuremamine and propadiene

yuremamine has been researched along with propadiene* in 1 studies

Other Studies

1 other study(ies) available for yuremamine and propadiene

Article	Year
Asymmetric synthesis of N-allylic indoles via regio- and enantioselective allylation of aryl hydrazines. Nature communications, 2015, Jul-03, Volume: 6 The asymmetric synthesis of N-allylic indoles is important for natural product synthesis and pharmaceutical research. The regio- and enantioselective N-allylation of indoles is a true challenge due to the favourable C3-allylation. We develop here a new strategy to the asymmetric synthesis of N-allylic indoles via rhodium-catalysed N-selective coupling of aryl hydrazines with allenes followed by Fischer indolization. The exclusive N-selectivities and good to excellent enantioselectivities are achieved applying a rhodium(I)/DTBM-Segphos or rhodium(I)/DTBM-Binap catalyst. This method permits the practical synthesis of valuable chiral N-allylated indoles, and avoids the N- or C-selectivity issue. Topics: Alkadienes; Allyl Compounds; Benzoxazines; Catalysis; Hydrazines; Indoles; Morpholines; Naphthalenes; Plant Extracts; Rhodium; Stereoisomerism; Vincamine	2015

Article

Year

Asymmetric synthesis of N-allylic indoles via regio- and enantioselective allylation of aryl hydrazines.

Nature communications, 2015, Jul-03, Volume: 6

The asymmetric synthesis of N-allylic indoles is important for natural product synthesis and pharmaceutical research. The regio- and enantioselective N-allylation of indoles is a true challenge due to the favourable C3-allylation. We develop here a new strategy to the asymmetric synthesis of N-allylic indoles via rhodium-catalysed N-selective coupling of aryl hydrazines with allenes followed by Fischer indolization. The exclusive N-selectivities and good to excellent enantioselectivities are achieved applying a rhodium(I)/DTBM-Segphos or rhodium(I)/DTBM-Binap catalyst. This method permits the practical synthesis of valuable chiral N-allylated indoles, and avoids the N- or C-selectivity issue.

Topics: Alkadienes; Allyl Compounds; Benzoxazines; Catalysis; Hydrazines; Indoles; Morpholines; Naphthalenes; Plant Extracts; Rhodium; Stereoisomerism; Vincamine

2015