xantphos has been researched along with allyl-alcohol* in 1 studies
1 other study(ies) available for xantphos and allyl-alcohol
| Article | Year |
|---|---|
Dual palladium- and proline-catalyzed allylic alkylation of enolizable ketones and aldehydes with allylic alcohols.
The dual Pd/proline-catalyzed alpha-allylation reaction of a variety of enolizable ketones and aldehydes with allylic alcohols is described. In this reaction, the choice of a large-bite angle ligand Xantphos and proline as the organocatalyst was essential for generation of the crucial pi-allyl Pd intermediate from allylic alcohol, followed by nucleophilic attack of the enamine formed in situ from the corresponding enolizable carbonyl substrate and proline. Topics: Aldehydes; Alkylation; Catalysis; Combinatorial Chemistry Techniques; Ketones; Molecular Structure; Palladium; Phosphines; Proline; Propanols; Stereoisomerism; Xanthenes | 2009 |