viridiofungin-a has been researched along with titanium-tetrachloride* in 1 studies
1 other study(ies) available for viridiofungin-a and titanium-tetrachloride
Article | Year |
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A stereoselective synthesis of (-)-viridiofungin A utilizing a TiCl(4)-promoted asymmetric multicomponent reaction.
A stereoselective synthesis of (-)-viridiofungin A is described. The convergent synthesis utilized a unique highly diastereoselective multicomponent reaction between optically active phenyldihydrofuran and an α-ketoester to provide two chiral centers including a quarternary carbon center in a single step. Other key steps include an acyloxycarbonium ion-mediated tetrahydrofuran ring-opening reaction and a Julia-Kocienski olefination. Topics: Citrates; Molecular Structure; Stereoisomerism; Titanium; Tyrosine | 2012 |