viridinomycin and isoprene

viridinomycin has been researched along with isoprene* in 1 studies

Other Studies

1 other study(ies) available for viridinomycin and isoprene

Article	Year
Pd-catalyzed asymmetric allylic alkylation. A short route to the cyclopentyl core of viridenomycin. Organic letters, 2003, May-01, Volume: 5, Issue:9 A palladium-catalyzed asymmetric allylic alkylation effects a dynamic kinetic asymmetric transformation of racemic isoprene monoepoxide and a surrogate for Nazarov's reagent in which a quaternary center is created with exellent ee. The resultant adduct allows easy access to a substrate for ring-closing metathesis to form a cyclopentenone and sets the stage for an 11-step synthesis of the cyclopentyl core of the antibiotic antitumor agent viridenomycin. [reaction: see text] Topics: Alkylation; Allyl Compounds; Antibiotics, Antineoplastic; Butadienes; Catalysis; Cyclization; Cyclopentanes; Epoxy Compounds; Hemiterpenes; Lactams; Organometallic Compounds; Palladium; Pentanes; Stereoisomerism	2003

Article

Year

Pd-catalyzed asymmetric allylic alkylation. A short route to the cyclopentyl core of viridenomycin.

Organic letters, 2003, May-01, Volume: 5, Issue:9

A palladium-catalyzed asymmetric allylic alkylation effects a dynamic kinetic asymmetric transformation of racemic isoprene monoepoxide and a surrogate for Nazarov's reagent in which a quaternary center is created with exellent ee. The resultant adduct allows easy access to a substrate for ring-closing metathesis to form a cyclopentenone and sets the stage for an 11-step synthesis of the cyclopentyl core of the antibiotic antitumor agent viridenomycin. [reaction: see text]

Topics: Alkylation; Allyl Compounds; Antibiotics, Antineoplastic; Butadienes; Catalysis; Cyclization; Cyclopentanes; Epoxy Compounds; Hemiterpenes; Lactams; Organometallic Compounds; Palladium; Pentanes; Stereoisomerism

2003