tris(dibenzylideneacetone)dipalladium has been researched along with acetyl-chloride* in 1 studies
1 other study(ies) available for tris(dibenzylideneacetone)dipalladium and acetyl-chloride
| Article | Year |
|---|---|
Pd2(dba)3/P(MeNCH2CH2)3N·HCl-mediated Stille cross-coupling of [1-11C]acetyl chloride with aryl and heteroaryl stannanes.
Developments in the Stille cross-coupling of [1-11C]acetyl chloride with tributylphenylstannane mediated by the Pd2(dba)3/P(MeNCH2CH2)3N·HClsystem are reported.. The reaction conditions for the cross-coupling of [1-11C]acetyl chloride with tributylphenylstannane were optimized, and the reaction scope was investigated.. The cross-couplings of [1-11C]acetyl chloride with a range of aryl and heteroaryl stannanes were performed with good to excellent radiochemical conversions using the developed method.. A highly efficient method for the Stille cross-coupling of [1-11C]acetyl chloride with organostannanes was demonstrated. It is anticipated that our method will be an attractive addition to the carbon-11-labeling procedures available for the synthesis of positron emission tomography probes. Topics: Acetates; Carbon Radioisotopes; Catalysis; Chlorides; Organometallic Compounds; Organophosphorus Compounds; Solvents; Tin Compounds | 2012 |