tris(4-bromophenyl)ammoniumyl-hexachloroantimonate and azetidine

tris(4-bromophenyl)ammoniumyl-hexachloroantimonate has been researched along with azetidine* in 1 studies

Other Studies

1 other study(ies) available for tris(4-bromophenyl)ammoniumyl-hexachloroantimonate and azetidine

Article	Year
Cycloreversion of azetidines via oxidative electron transfer. steady-state and time-resolved studies. Organic letters, 2008, Nov-20, Volume: 10, Issue:22 Cycloreversion of cis- and trans-1,2,3-triphenylazetidine (c-2 and t-2) is achieved by electron transfer to (tris(4-bromophenyl)aminium radical cation (5 (+)). Stepwise C-N and C-C bond cleavage of azetidine radical cations leads to cis- and trans-stilbene, together with N-benzylideneaniline, as final products. Mechanistic evidence is provided by quenching studies, using laser flash photolysis to generate 5 (+) from its neutral precursor. Topics: Azetidines; Cyclization; Electron Transport; Organometallic Compounds; Quaternary Ammonium Compounds; Spectrophotometry, Ultraviolet; Stereoisomerism; Time Factors	2008

Article

Year

Cycloreversion of azetidines via oxidative electron transfer. steady-state and time-resolved studies.

Organic letters, 2008, Nov-20, Volume: 10, Issue:22

Cycloreversion of cis- and trans-1,2,3-triphenylazetidine (c-2 and t-2) is achieved by electron transfer to (tris(4-bromophenyl)aminium radical cation (5 (*+)). Stepwise C-N and C-C bond cleavage of azetidine radical cations leads to cis- and trans-stilbene, together with N-benzylideneaniline, as final products. Mechanistic evidence is provided by quenching studies, using laser flash photolysis to generate 5 (*+) from its neutral precursor.

Topics: Azetidines; Cyclization; Electron Transport; Organometallic Compounds; Quaternary Ammonium Compounds; Spectrophotometry, Ultraviolet; Stereoisomerism; Time Factors

2008