Page last updated: 2024-08-25

trimethylsilyl cyanide and cyanides

trimethylsilyl cyanide has been researched along with cyanides in 45 studies

Research

Studies (45)

TimeframeStudies, this research(%)All Research%
pre-19901 (2.22)18.7374
1990's0 (0.00)18.2507
2000's22 (48.89)29.6817
2010's18 (40.00)24.3611
2020's4 (8.89)2.80

Authors

AuthorsStudies
Inoue, K; Matsuura, T; Moriyama, H; Nagata, R; Nakagawa, H; Saito, I1
Hayashi, M; Inoue, K; Kawabata, H1
Jacobsen, EN; Schaus, SE1
Curran, DP; Du, W; Hamashima, Y; Kanai, M; Masumoto, S; Shibasaki, M; Yabu, K; Yamasaki, S1
Hayashi, M; Kawabata, H; Nakayama, SZ1
Deng, H; Hoveyda, AH; Isler, MP; Snapper, ML1
Deng, L; Hong, R; Tian, SK1
Liu, L; Pu, L; Qin, YC1
Fuerst, DE; Jacobsen, EN1
Fujimori, I; Kanai, M; Mita, T; Shibasaki, M; Wada, R; Wen, J1
Chun, MW; Jeong, LS; Kim, BR; Kim, JH; Kim, MJ1
Gallou, F; Reeves, JT; Senanayake, CH; Song, JJ; Tan, Z; Yee, NK1
Shenoy, SR; Smith, DM; Woerpel, KA1
Kultyshev, R; Mathew, T; Olah, GA; Panja, C; Prakash, GK; Surampudi, V; Vaghoo, H1
Feng, X; Gou, S; Hu, X; Huang, X; Jiang, J; Liu, X; Wang, J1
Wittmann, V; Worch, M1
Chen, CA; Gau, HM; Lan, J; Wei, S; Xi, P; Yang, F; Yang, L; You, J1
Jacobsen, EN; Mazet, C1
Abdi, SH; Agrawal, S; Jasra, RV; Khan, NU; Kureshy, RI; Prathap, KJ1
Hachiya, I; Matsuda, Y; Mizota, I; Shimizu, M1
Chen, G; Ding, K; Wang, Z; Wu, J1
Cai, Y; Feng, X; Lin, L; Liu, X; Shen, K1
Matsukawa, S; Tsukamoto, K1
Ma, JA; Nie, J; Wang, T; Zhang, GW; Zheng, DH1
Gatti, FG; Lesma, G; Pilati, T; Sacchetti, A; Silvani, A; Trucchi, B1
Hausmann, H; Kotke, M; Lippert, KM; Schreiner, PR; Zhang, Z1
Hirano, T; Kamata, K; Kikukawa, Y; Mizuno, N; Sugawa, M; Suzuki, K; Yamaguchi, K1
Dilman, AD; Kosobokov, MD; Levin, VV; Struchkova, MI1
Fan, W; Kong, S; Miao, Z; Wu, G1
Chaudhary, V; Guchhait, SK; Madaan, C1
Hirose, T; Kawamata, H; Kodama, K; Takahashi, N1
Abdi, SH; Bajaj, HC; Ganguly, B; Khan, NU; Kureshy, RI; Sadhukhan, A; Sahu, D; Suresh, E1
Bak, S; Engelsen, SB; Khakimov, B; Motawia, MS1
Fukuyama, T; Kaise, H; Shimokawa, J1
Liu, X; Wang, R; Zhang, J1
Motawia, MS; Møller, BL; Olsen, CE1
Karimi, B; Mobaraki, A; Movassagh, B1
Chaudhary, V; Guchhait, SK1
Chen, D; Xu, MH1
Cui, X; Xu, MC; Yao, RX; Zhang, LJ; Zhang, XM1
Boyko, W; Dougherty, W; Giovine, M; Giuliano, R; Kassel, S; Rotella, M1
Angamuthu, V; Tai, DF1
Guedes da Silva, MFC; Karmakar, A; Paul, A; Pombeiro, AJL; Sabatini, EP1
Cao, S; Chen, R; Li, Y; Si, H; Teng, X; Yuan, W; Zhu, Y1
Chen, T; Han, Y; Huang, T; Li, C; Li, W; Liu, L; Tang, Z; Xu, T; Zhang, K1

Other Studies

45 other study(ies) available for trimethylsilyl cyanide and cyanides

ArticleYear
New singlet oxygen source and trapping reagent for peroxide intermediates.
    Free radical research communications, 1987, Volume: 2, Issue:4-6

    Topics: Cyanides; Electrons; Free Radicals; Models, Chemical; Oxidation-Reduction; Oxygen; Peroxides; Photochemistry; Solubility; Solvents; Trimethylsilyl Compounds; Tryptophan

1987
Thermal C-glycosylation of D-glucal with trimethylsilyl cyanide.
    Carbohydrate research, 2000, Mar-24, Volume: 325, Issue:1

    Topics: Calcium Gluconate; Cyanides; Glycosides; Glycosylation; Magnetic Resonance Spectroscopy; Trimethylsilyl Compounds

2000
Asymmetric ring opening of meso epoxides with TMSCN catalyzed by (pybox)lanthanide complexes.
    Organic letters, 2000, Apr-06, Volume: 2, Issue:7

    Topics: Catalysis; Chromatography, Gas; Cyanides; Epoxy Compounds; Metals, Rare Earth; Trimethylsilyl Compounds

2000
Switching enantiofacial selectivities using one chiral source: catalytic enantioselective synthesis of the key intermediate for (20S)-camptothecin family by (S)-selective cyanosilylation of ketones.
    Journal of the American Chemical Society, 2001, Oct-10, Volume: 123, Issue:40

    Topics: Camptothecin; Cyanides; Glucose; Stereoisomerism; Trimethylsilyl Compounds

2001
Stereoselective C-glycosidation of unprotected D-glycals with trimethylsilyl cyanide.
    Chirality, 2003, Volume: 15, Issue:1

    Topics: Cyanides; Glycosides; Glycosylation; Indicators and Reagents; Molecular Structure; Stereoisomerism; Trimethylsilyl Compounds

2003
Aluminum-catalyzed asymmetric addition of TMSCN to aromatic and aliphatic ketones promoted by an easily accessible and recyclable peptide ligand.
    Angewandte Chemie (International ed. in English), 2002, Mar-15, Volume: 41, Issue:6

    Topics: Alkylation; Aluminum; Catalysis; Conservation of Natural Resources; Cyanides; Ketones; Ligands; Peptides; Trimethylsilyl Compounds

2002
Catalytic asymmetric cyanosilylation of ketones with chiral Lewis base.
    Journal of the American Chemical Society, 2003, Aug-20, Volume: 125, Issue:33

    Topics: Acetals; Amino Alcohols; Cinchona Alkaloids; Cyanides; Ketones; Stereoisomerism; Trimethylsilyl Compounds

2003
On-step synthesis of a bifunctional BINOL ligand for the highly enantioselective cyanation of aliphatic aldehydes.
    Organic letters, 2005, Jun-09, Volume: 7, Issue:12

    Topics: Aldehydes; Catalysis; Combinatorial Chemistry Techniques; Cyanides; Ligands; Molecular Structure; Naphthols; Stereoisomerism; Trimethylsilyl Compounds

2005
Thiourea-catalyzed enantioselective cyanosilylation of ketones.
    Journal of the American Chemical Society, 2005, Jun-29, Volume: 127, Issue:25

    Topics: Catalysis; Cyanides; Ketones; Molecular Conformation; Stereoisomerism; Thiourea; Trimethylsilyl Compounds

2005
Catalytic enantioselective desymmetrization of meso-N-acylaziridines with TMSCN.
    Journal of the American Chemical Society, 2005, Aug-17, Volume: 127, Issue:32

    Topics: Amino Acids, Cyclic; Aziridines; Catalysis; Cyanides; Isomerism; Trimethylsilyl Compounds

2005
Synthesis of homo-N-nucleoside with 1,2,4-triazole-3-carboxamide.
    Nucleosides, nucleotides & nucleic acids, 2005, Volume: 24, Issue:5-7

    Topics: Antiviral Agents; Chemistry, Pharmaceutical; Cyanides; DNA Replication; Drug Design; Models, Chemical; Nucleic Acid Conformation; Nucleosides; Nucleotides; Ribavirin; Triazoles; Trimethylsilyl Compounds

2005
Activation of TMSCN by N-heterocyclic carbenes for facile cyanosilylation of carbonyl compounds.
    The Journal of organic chemistry, 2006, Feb-03, Volume: 71, Issue:3

    Topics: Acetophenones; Benzaldehydes; Catalysis; Cyanides; Cyclization; Hydrocarbons; Methane; Molecular Structure; Nitriles; Trimethylsilyl Compounds

2006
Nucleophilic additions of trimethylsilyl cyanide to cyclic oxocarbenium ions: evidence for the loss of stereoselectivity at the limits of diffusion control.
    Journal of the American Chemical Society, 2006, Jul-05, Volume: 128, Issue:26

    Topics: Acetals; Cyanides; Diffusion; Ions; Models, Chemical; Molecular Conformation; Organosilicon Compounds; Stereoisomerism; Trimethylsilyl Compounds

2006
Effect of carbonates/phosphates as nucleophilic catalysts in dimethylformamide for efficient cyanosilylation of aldehydes and ketones.
    Proceedings of the National Academy of Sciences of the United States of America, 2007, Feb-27, Volume: 104, Issue:9

    Topics: Aldehydes; Carbonates; Catalysis; Cyanides; Dimethylformamide; Ketones; Models, Chemical; Phosphates; Potassium; Trimethylsilyl Compounds

2007
Asymmetric activation of tropos 2,2'-biphenol with cinchonine generates an effective catalyst for the asymmetric strecker reaction of N-tosyl-protected aldimines and ketoimines.
    Angewandte Chemie (International ed. in English), 2007, Volume: 46, Issue:44

    Topics: Amino Acids; Catalysis; Chemistry, Organic; Cinchona Alkaloids; Cyanides; Imines; Ketones; Models, Chemical; Phenols; Stereoisomerism; Temperature; Trimethylsilyl Compounds

2007
Unexpected formation of complex bridged tetrazoles via intramolecular 1,3-dipolar cycloaddition of 1,2-O-cyanoalkylidene derivatives of 3-azido-3-deoxy-D-allose.
    Carbohydrate research, 2008, Aug-11, Volume: 343, Issue:12

    Topics: Azides; Cyanides; Deoxy Sugars; Tetrazoles; Trimethylsilyl Compounds

2008
A new strategy for designing non-C2-symmetric monometallic bifunctional catalysts and their application in enantioselective cyanation of aldehydes.
    Chemistry (Weinheim an der Bergstrasse, Germany), 2008, Volume: 14, Issue:7

    Topics: Aldehydes; Catalysis; Cyanides; Imidazoles; Ligands; Molecular Conformation; Naphthols; Nitriles; Organometallic Compounds; Stereoisomerism; Titanium; Trimethylsilyl Compounds

2008
Dinuclear {(salen)Al} complexes display expanded scope in the conjugate cyanation of alpha,beta-unsaturated imides.
    Angewandte Chemie (International ed. in English), 2008, Volume: 47, Issue:9

    Topics: Catalysis; Cyanides; Ethylenediamines; Imides; Molecular Structure; Organometallic Compounds; Trimethylsilyl Compounds

2008
Enantioselective cyanosilylation of ketones catalyzed by recyclable polymeric and dimeric Mn(III) salen complexes at room temperature.
    Chirality, 2009, Volume: 21, Issue:2

    Topics: Catalysis; Cyanides; Dimerization; Ethylenediamines; Ketones; Manganese; Organometallic Compounds; Polymers; Spectrophotometry, Infrared; Stereoisomerism; Substrate Specificity; Temperature; Trimethylsilyl Compounds

2009
Synthesis of N-allylideneamines and their use for the double nucleophilic addition of ketene silyl (thio)acetals and trimethylsilyl cyanide.
    Organic letters, 2008, Sep-18, Volume: 10, Issue:18

    Topics: Acetals; Acrolein; Amines; Cyanides; Ethylenes; Ketones; Silicon; Trimethylsilyl Compounds

2008
Facile preparation of alpha-aryl nitriles by direct cyanation of alcohols with TMSCN under the catalysis of InX3.
    Organic letters, 2008, Oct-16, Volume: 10, Issue:20

    Topics: Alcohols; Bromine Compounds; Catalysis; Cyanides; Furans; Indium; Molecular Structure; Nitriles; Trimethylsilyl Compounds

2008
Facile and efficient enantioselective Strecker reaction of ketimines by chiral sodium phosphate.
    Chemistry (Weinheim an der Bergstrasse, Germany), 2009, Jun-08, Volume: 15, Issue:24

    Topics: Catalysis; Cyanides; Imines; Metals, Alkali; Molecular Structure; Naphthalenes; Nitriles; Organophosphates; Phosphates; Stereoisomerism; Trimethylsilyl Compounds

2009
TTMPP: An efficient organocatalyst in the ring-opening of aziridines with silylated nucleophiles.
    Organic & biomolecular chemistry, 2009, Sep-21, Volume: 7, Issue:18

    Topics: Aziridines; Catalysis; Cyanides; Organosilicon Compounds; Phosphines; Trimethylsilyl Compounds

2009
Brønsted acid-catalyzed efficient Strecker reaction of ketones, amines and trimethylsilyl cyanide.
    Organic & biomolecular chemistry, 2010, Mar-21, Volume: 8, Issue:6

    Topics: Acids; Amines; Catalysis; Cyanides; Ketones; Magnetic Resonance Spectroscopy; Spectrometry, Mass, Electrospray Ionization; Trimethylsilyl Compounds

2010
Addition of TMSCN to chiral ketimines derived from isatin. Synthesis of an oxindole-based peptidomimetic and a bioactive spirohydantoin.
    Organic & biomolecular chemistry, 2011, Aug-07, Volume: 9, Issue:15

    Topics: Crystallography, X-Ray; Cyanides; Hydantoins; Imines; Indoles; Isatin; Molecular Structure; Nitriles; Oxindoles; Peptidomimetics; Spiro Compounds; Stereoisomerism; Trimethylsilyl Compounds

2011
Cooperative thiourea-Brønsted acid organocatalysis: enantioselective cyanosilylation of aldehydes with TMSCN.
    The Journal of organic chemistry, 2011, Dec-02, Volume: 76, Issue:23

    Topics: Acids; Aldehydes; Catalysis; Cyanides; Molecular Structure; Nitriles; Stereoisomerism; Thiourea; Trimethylsilyl Compounds

2011
Cyanosilylation of carbonyl compounds with trimethylsilyl cyanide catalyzed by an yttrium-pillared silicotungstate dimer.
    Angewandte Chemie (International ed. in English), 2012, Apr-10, Volume: 51, Issue:15

    Topics: Catalysis; Cyanides; Hydrocarbons; Ketones; Models, Molecular; Silicon; Trimethylsilyl Compounds; Tungsten; Tungsten Compounds; Yttrium

2012
Difluoro(trimethylsilyl)acetonitrile: synthesis and fluoroalkylation reactions.
    The Journal of organic chemistry, 2012, Jul-06, Volume: 77, Issue:13

    Topics: Acetonitriles; Aldehydes; Alkylation; Cyanides; Hydrocarbons, Fluorinated; Imines; Molecular Structure; Stereoisomerism; Tosyl Compounds; Trimethylsilyl Compounds

2012
Enantioselective synthesis of tertiary α-hydroxy phosphonates catalyzed by carbohydrate/cinchona alkaloid thiourea organocatalysts.
    Angewandte Chemie (International ed. in English), 2012, Aug-27, Volume: 51, Issue:35

    Topics: Carbohydrates; Catalysis; Cinchona Alkaloids; Cyanides; Organophosphonates; Stereoisomerism; Thiourea; Trimethylsilyl Compounds

2012
A chemoselective Ugi-type reaction in water using TMSCN as a functional isonitrile equivalent: generation of heteroaromatic molecular diversity.
    Organic & biomolecular chemistry, 2012, Dec-14, Volume: 10, Issue:46

    Topics: Aldehydes; Benzamidines; Cyanides; Cyclization; Fluorides; Imidazoles; Magnetic Resonance Spectroscopy; Molecular Structure; Nitriles; Potassium Compounds; Stereoisomerism; Trimethylsilyl Compounds; Water

2012
Cyanative self-condensation of aromatic aldehydes promoted by VO(O(i)Pr)(3)-Lewis base as a cooperative catalyst.
    Organic & biomolecular chemistry, 2012, Dec-21, Volume: 10, Issue:47

    Topics: Aldehydes; Catalysis; Cyanides; Lewis Bases; Molecular Structure; Nitriles; Oxygen; Solvents; Trimethylsilyl Compounds; Vanadates

2012
Oxazoline-based organocatalyst for enantioselective strecker reactions: a protocol for the synthesis of levamisole.
    Chemistry (Weinheim an der Bergstrasse, Germany), 2013, Oct-11, Volume: 19, Issue:42

    Topics: Benzhydryl Compounds; Catalysis; Cyanides; Imines; Levamisole; Molecular Structure; Nitriles; Oxazoles; Quantum Theory; Stereoisomerism; Trimethylsilyl Compounds; X-Ray Diffraction

2013
The use of trimethylsilyl cyanide derivatization for robust and broad-spectrum high-throughput gas chromatography-mass spectrometry based metabolomics.
    Analytical and bioanalytical chemistry, 2013, Volume: 405, Issue:28

    Topics: Blueberry Plants; Cyanides; Fruit; Gas Chromatography-Mass Spectrometry; Metabolomics; Plant Extracts; Trimethylsilyl Compounds

2013
TMSCN/DBU-mediated facile redox transformation of α,β-unsaturated aldehydes to carboxylic acid derivatives.
    Organic letters, 2014, Feb-07, Volume: 16, Issue:3

    Topics: Aldehydes; Carboxylic Acids; Cyanides; Kinetics; Molecular Structure; Oxidation-Reduction; Stereoisomerism; Thermodynamics; Trimethylsilyl Compounds

2014
Magnesium complexes as highly effective catalysts for conjugate cyanation of α,β-unsaturated amides and ketones.
    Chemistry (Weinheim an der Bergstrasse, Germany), 2014, Apr-22, Volume: 20, Issue:17

    Topics: Alkenes; Amides; Catalysis; Coordination Complexes; Cyanides; Ketones; Magnesium; Naphthols; Trimethylsilyl Compounds

2014
Synthesis of the allelochemical alliarinoside present in garlic mustard (Alliaria petiolata), an invasive plant species in North America.
    Carbohydrate research, 2014, Jul-23, Volume: 394

    Topics: Brassicaceae; Chemistry Techniques, Synthetic; Cyanides; Glucosides; Introduced Species; Magnetic Resonance Spectroscopy; Nitriles; North America; Stereoisomerism; Trimethylsilyl Compounds

2014
Magnetic solid sulfonic acid decorated with hydrophobic regulators: a combinatorial and magnetically separable catalyst for the synthesis of α-aminonitriles.
    ACS combinatorial science, 2014, Jul-14, Volume: 16, Issue:7

    Topics: Aldehydes; Amines; Catalysis; Cyanides; Hydrophobic and Hydrophilic Interactions; Ketones; Magnetic Phenomena; Molecular Structure; Nitriles; Organometallic Compounds; Sulfonic Acids; Trimethylsilyl Compounds

2014
Desilylative activation of TMSCN in chemoselective Strecker-Ugi type reaction: functional fused imidazoles as building blocks as an entry route to annulated purines.
    Organic & biomolecular chemistry, 2014, Sep-14, Volume: 12, Issue:34

    Topics: Amidines; Catalysis; Cyanides; Glyoxylates; Imidazoles; Molecular Structure; Piperazines; Purines; Trimethylsilyl Compounds

2014
Lewis acid promoted diastereoselective addition of TMSCN and TMSCF3 to isatin-derived N-sulfinyl ketimines: synthesis of optically active tetrasubstituted 3-aminooxindoles.
    The Journal of organic chemistry, 2014, Aug-15, Volume: 79, Issue:16

    Topics: Butanes; Catalysis; Cyanides; Hydrocarbons, Fluorinated; Imines; Indoles; Isatin; Lewis Acids; Methylation; Molecular Structure; Nitriles; Silica Gel; Stereoisomerism; Sulfonamides; Trimethylsilyl Compounds

2014
Solvent-free heterogeneous catalysis for cyanosilylation in a dynamic cobalt-MOF.
    Dalton transactions (Cambridge, England : 2003), 2015, Jul-28, Volume: 44, Issue:28

    Topics: Aldehydes; Catalysis; Cobalt; Crystallography, X-Ray; Cyanides; Organometallic Compounds; Powder Diffraction; Trimethylsilyl Compounds; X-Ray Diffraction

2015
Synthesis and x-ray crystallographic analysis of 4,6-di-O-acetyl-2,3-dideoxy-α-D-threo-hexopyranosyl cyanide.
    Carbohydrate research, 2016, Apr-29, Volume: 425

    Topics: Carbohydrate Conformation; Crystallography, X-Ray; Cyanides; Hexoses; Magnetic Resonance Spectroscopy; Models, Molecular; Nitriles; Trimethylsilyl Compounds

2016
Synthesis of Natural (-)-Antrocin and its Enantiomer via Stereoselective Aldol Reaction.
    Molecules (Basel, Switzerland), 2020, Feb-14, Volume: 25, Issue:4

    Topics: Biological Products; Breast Neoplasms; Cell Line, Tumor; Cell Proliferation; Cyanides; Female; Humans; Lactones; Neoplasm Metastasis; Sesquiterpenes; Stereoisomerism; Tartrates; Trimethylsilyl Compounds

2020
Pyrene Carboxylate Ligand Based Coordination Polymers for Microwave-Assisted Solvent-Free Cyanosilylation of Aldehydes.
    Molecules (Basel, Switzerland), 2021, Feb-19, Volume: 26, Issue:4

    Topics: Aldehydes; Catalysis; Cyanides; Hydrogen Bonding; Ligands; Microwaves; Models, Molecular; Molecular Conformation; Polymers; Pyrenes; Solvents; Thermogravimetry; Trimethylsilyl Compounds

2021
Photoredox/copper cocatalyzed domino cyclization of oxime esters with TMSCN: access to antifungal active tetrasubstituted pyrazines.
    Chemical communications (Cambridge, England), 2022, Jun-23, Volume: 58, Issue:51

    Topics: Antifungal Agents; Catalysis; Copper; Cyanides; Cyclization; Esters; Oximes; Pyrazines; Trimethylsilyl Compounds

2022
Palladium-Catalyzed Decarbonylative Cyanation of Carboxylic Acids with TMSCN.
    The Journal of organic chemistry, 2022, 09-02, Volume: 87, Issue:17

    Topics: Carboxylic Acids; Catalysis; Cyanides; Palladium; Trimethylsilyl Compounds

2022