triazacyclononane and ethylene

triazacyclononane has been researched along with ethylene* in 1 studies

Other Studies

1 other study(ies) available for triazacyclononane and ethylene

Article	Year
Synthesis and characterization of a binuclear iron(III) complex bridged by 1-aminocyclopropane-1-carboxylic acid. Ethylene production in the presence of hydrogen peroxide. Inorganic chemistry, 2009, May-04, Volume: 48, Issue:9 A mu-oxo-diiron(III) complex bridged by two molecules of 1-aminocyclopropane-1-carboxylic acid (ACCH) was prepared with the ligand 1,4,7-triazacyclononane (TACN): [(TACN)Fe(2)(mu-O)(mu-ACCH)(2)](ClO(4))(4) x 2 H(2)O (1). This complex was characterized, and its crystal structure was solved. The bridging amino acid moieties were found in their zwitterionic forms (noted as ACCH). Reactivity assays were performed in the presence of hydrogen peroxide, and 1 turned out to be the first example of a well-characterized iron-ACCH complex able to produce ethylene from the bound ACCH moiety. The reaction requires the presence of a few equivalents of base, probably involved in the deprotonation of the amine groups of the ACCH bridges. Topics: Amino Acids, Cyclic; Aza Compounds; Catalysis; Crystallography, X-Ray; Ethylenes; Ferric Compounds; Hydrogen Peroxide; Iron; Piperidines	2009

Article

Year

Synthesis and characterization of a binuclear iron(III) complex bridged by 1-aminocyclopropane-1-carboxylic acid. Ethylene production in the presence of hydrogen peroxide.

Inorganic chemistry, 2009, May-04, Volume: 48, Issue:9

A mu-oxo-diiron(III) complex bridged by two molecules of 1-aminocyclopropane-1-carboxylic acid (ACCH) was prepared with the ligand 1,4,7-triazacyclononane (TACN): [(TACN)Fe(2)(mu-O)(mu-ACCH)(2)](ClO(4))(4) x 2 H(2)O (1). This complex was characterized, and its crystal structure was solved. The bridging amino acid moieties were found in their zwitterionic forms (noted as ACCH). Reactivity assays were performed in the presence of hydrogen peroxide, and 1 turned out to be the first example of a well-characterized iron-ACCH complex able to produce ethylene from the bound ACCH moiety. The reaction requires the presence of a few equivalents of base, probably involved in the deprotonation of the amine groups of the ACCH bridges.

Topics: Amino Acids, Cyclic; Aza Compounds; Catalysis; Crystallography, X-Ray; Ethylenes; Ferric Compounds; Hydrogen Peroxide; Iron; Piperidines

2009