tmpmgcl.licl has been researched along with coelenterazine* in 1 studies
1 other study(ies) available for tmpmgcl.licl and coelenterazine
Article | Year |
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Regio- and chemoselective multiple functionalization of chloropyrazine derivatives. Application to the synthesis of coelenterazine.
Successive regio- and chemoselective metalations of chloropyrazines using TMPMgCl x LiCl and TMPZnCl x LiCl furnish, after trapping with electrophiles, highly functionalized pyrazines in high yields. Application to a synthesis of coelenterazine, a bioluminescent natural product in jellyfish Aequorea victoria, in nine steps (9% overall yield) is reported. Topics: Animals; Imidazoles; Organometallic Compounds; Pyrazines; Pyruvaldehyde; Scyphozoa | 2009 |