thiourea and benzyne

thiourea has been researched along with benzyne* in 1 studies

Other Studies

1 other study(ies) available for thiourea and benzyne

Article	Year
Insertion of arynes into thioureas: a new amidine synthesis. Organic letters, 2011, Sep-16, Volume: 13, Issue:18 Arynes, generated from trimethylsilyl phenyltriflate precursors, have been found to react with thioureas via a formal π-insertion into the C═S bond. The reaction contrasts with that of ureas, which proceeds via benzyne σ-insertion into the C-N bond, and represents a new, operationally simple route to functionalized amidines. Topics: Amidines; Benzene Derivatives; Crystallography, X-Ray; Models, Molecular; Molecular Structure; Stereoisomerism; Thiourea	2011

Article

Year

Insertion of arynes into thioureas: a new amidine synthesis.

Organic letters, 2011, Sep-16, Volume: 13, Issue:18

Arynes, generated from trimethylsilyl phenyltriflate precursors, have been found to react with thioureas via a formal π-insertion into the C═S bond. The reaction contrasts with that of ureas, which proceeds via benzyne σ-insertion into the C-N bond, and represents a new, operationally simple route to functionalized amidines.

Topics: Amidines; Benzene Derivatives; Crystallography, X-Ray; Models, Molecular; Molecular Structure; Stereoisomerism; Thiourea

2011