thiourea and 4-nitrophthalimide

thiourea has been researched along with 4-nitrophthalimide* in 1 studies

Other Studies

1 other study(ies) available for thiourea and 4-nitrophthalimide

Article	Year
Colorimetric detection of achiral anions and chiral carboxylates by a chiral thiourea-phthalimide dyad. Photochemical & photobiological sciences : Official journal of the European Photochemistry Association and the European Society for Photobiology, 2010, Oct-28, Volume: 9, Issue:10 The chiral chemosensor 1, based on a thiourea-activated phthalimide, is available by four reaction steps from 4-nitrophthalimide. 1 detects fluoride, chloride, acetate, and dihydrogen phosphate anions by changes in UV-vis absorption. Fluoride in excess induces deprotonation whereas the other anions show only complex formation in the ground state. (1)H-NMR studies confirm the formation of these H-bonded complexes and the fluoride-induced receptor deprotonation in the recognition process. Moderate chiral recognition was observed for sodium D/L-lactate with K(ass)(D)/K(ass)(L) = 1.93. Topics: Anions; Carboxylic Acids; Colorimetry; Kinetics; Magnetic Resonance Spectroscopy; Nitro Compounds; Phthalimides; Sodium Lactate; Spectrophotometry, Ultraviolet; Stereoisomerism; Thiourea	2010

Article

Year

Colorimetric detection of achiral anions and chiral carboxylates by a chiral thiourea-phthalimide dyad.

Photochemical & photobiological sciences : Official journal of the European Photochemistry Association and the European Society for Photobiology, 2010, Oct-28, Volume: 9, Issue:10

The chiral chemosensor 1, based on a thiourea-activated phthalimide, is available by four reaction steps from 4-nitrophthalimide. 1 detects fluoride, chloride, acetate, and dihydrogen phosphate anions by changes in UV-vis absorption. Fluoride in excess induces deprotonation whereas the other anions show only complex formation in the ground state. (1)H-NMR studies confirm the formation of these H-bonded complexes and the fluoride-induced receptor deprotonation in the recognition process. Moderate chiral recognition was observed for sodium D/L-lactate with K(ass)(D)/K(ass)(L) = 1.93.

Topics: Anions; Carboxylic Acids; Colorimetry; Kinetics; Magnetic Resonance Spectroscopy; Nitro Compounds; Phthalimides; Sodium Lactate; Spectrophotometry, Ultraviolet; Stereoisomerism; Thiourea

2010