thiazoline-2-thione has been researched along with iriomoteolide-1a* in 1 studies
1 other study(ies) available for thiazoline-2-thione and iriomoteolide-1a
Article | Year |
---|---|
Enantioselective synthesis of the C1-C6 and C7-C23 fragments of the proposed structure of iriomoteolide 1a.
Synthesis of the C1-C6 and C7-C23 fragments of the proposed structure of iriomoteolide 1a has been accomplished. Key steps include a cross metathesis to form the C15-C16 E olefin and a chelation controlled Grignard addition to form the tertiary alcohol at C14. Notably, 7 of the 9 stereocenters of the proposed structure have been set using various aldol reactions employing metallo enolates of thiazolidinethiones. Topics: Aldehydes; Macrolides; Molecular Structure; Stereoisomerism; Thiazolidines | 2012 |