thallusin and sclareol

thallusin has been researched along with sclareol* in 1 studies

Other Studies

1 other study(ies) available for thallusin and sclareol

Article	Year
Synthesis of ent-thallusin. Organic letters, 2006, May-11, Volume: 8, Issue:10 [reaction: see text] A three-step route from sclareol oxide (6) to bromo ester 4 in 53% overall yield was achieved using the efficient oxidation of an allylic bromide to an enal with bis(2,4,6-trimethylpyridine)silver(I) hexafluorophosphate in DMSO. Stille coupling of bromo ester 4 with stannylpyridine 5 gave the trimethyl ester of ent-thallusin in 54-92% yield by the stoichiometric conversion of 4 to a vinyl palladium intermediate prior to the addition of 5 to the reaction. Topics: Chlorophyta; Diterpenes; Molecular Structure; Palladium; Pyridines; Stereoisomerism	2006

Article

Year

Organic letters, 2006, May-11, Volume: 8, Issue:10

[reaction: see text] A three-step route from sclareol oxide (6) to bromo ester 4 in 53% overall yield was achieved using the efficient oxidation of an allylic bromide to an enal with bis(2,4,6-trimethylpyridine)silver(I) hexafluorophosphate in DMSO. Stille coupling of bromo ester 4 with stannylpyridine 5 gave the trimethyl ester of ent-thallusin in 54-92% yield by the stoichiometric conversion of 4 to a vinyl palladium intermediate prior to the addition of 5 to the reaction.

Topics: Chlorophyta; Diterpenes; Molecular Structure; Palladium; Pyridines; Stereoisomerism

2006