tetrathiomolybdate has been researched along with benzyltriethylammonium* in 2 studies
2 other study(ies) available for tetrathiomolybdate and benzyltriethylammonium
| Article | Year |
|---|---|
Synthesis of mixed glycosyl disulfides/selenenylsulfides using benzyltriethylammonium tetrathiomolybdate as a sulfur transfer reagent.
An easy and mild method has been developed for the synthesis of mixed glycosyl disulfides/selenenylsulfides from glycosyl halides and diaryl/dialkyl dichalcogenides in the presence of benzyltriethylammonium tetrathiomolybdate [(BnEt3N)2MoS4]. The salient feature of this method is the sulfur transfer from [BnEt3N]2MoS4 to form glycosyl disulfides which with excess tetrathiomolybdate further undergo exchange reaction with other dichalcogenides in a one-pot operation. Topics: Chemistry Techniques, Synthetic; Disulfides; Glycosylation; Indicators and Reagents; Molybdenum; Quaternary Ammonium Compounds; Selenium; Stereoisomerism; Sulfur | 2015 |
De novo synthesis of 1-deoxythiosugars.
A short and efficient chemical synthesis of biologically potent and novel 1-deoxythiosugars is accomplished. Introduction of sulfur mediated by benzyltriethylammonium tetrathiomolybdate, as a sulfur transfer reagent through nucleophilic double displacement of tosylate in α,ω-di-O-tosyl aldonolactones in an intramolecular fashion is the key feature. The subsequent reduction of thiosugar lactones with borohydride exchange resin (BER) offers a number of deoxythiosugars in good overall yield. Topics: Borohydrides; Carbohydrates; Chemistry Techniques, Synthetic; Ion Exchange Resins; Lactones; Molybdenum; Quaternary Ammonium Compounds; Stereoisomerism; Sulfur | 2013 |