tetrabutylammonium-triphenyldifluorosilicate and dithiane

tetrabutylammonium-triphenyldifluorosilicate has been researched along with dithiane* in 1 studies

Other Studies

1 other study(ies) available for tetrabutylammonium-triphenyldifluorosilicate and dithiane

ArticleYear
Bu4N+ alkoxide-initiated/autocatalytic addition reactions with organotrimethylsilanes.
    The Journal of organic chemistry, 2014, Jun-20, Volume: 79, Issue:12

    The use of Me3SiO(-)/Bu4N(+) as a general activator of organotrimethylsilanes for addition reactions has been established. The broad scope of the method offers trimethylsilanes (including acetate, allyl, propargyl, benzyl, dithiane, heteroaryl, and aryl derivatives) as bench-stable organometallics that can be readily utilized as carbanion equivalents for synthesis. Reactions are achieved at rt without the requirement of specialized precautions that are commonplace for other organometallics.

    Topics: Catalysis; Cations; Molecular Structure; Organometallic Compounds; Organosilicon Compounds; Quaternary Ammonium Compounds; Quinolizines; Sulfur Compounds; Trimethylsilyl Compounds

2014