tetrabutylammonium-triphenyldifluorosilicate has been researched along with dithiane* in 1 studies
1 other study(ies) available for tetrabutylammonium-triphenyldifluorosilicate and dithiane
Article | Year |
---|---|
Bu4N+ alkoxide-initiated/autocatalytic addition reactions with organotrimethylsilanes.
The use of Me3SiO(-)/Bu4N(+) as a general activator of organotrimethylsilanes for addition reactions has been established. The broad scope of the method offers trimethylsilanes (including acetate, allyl, propargyl, benzyl, dithiane, heteroaryl, and aryl derivatives) as bench-stable organometallics that can be readily utilized as carbanion equivalents for synthesis. Reactions are achieved at rt without the requirement of specialized precautions that are commonplace for other organometallics. Topics: Catalysis; Cations; Molecular Structure; Organometallic Compounds; Organosilicon Compounds; Quaternary Ammonium Compounds; Quinolizines; Sulfur Compounds; Trimethylsilyl Compounds | 2014 |