tert-butoxide--potassium and vasicine

tert-butoxide--potassium has been researched along with vasicine* in 1 studies

Other Studies

1 other study(ies) available for tert-butoxide--potassium and vasicine

ArticleYear
Microwave assisted synthesis of phenanthridinones and dihydrophenanthridines by vasicine/KOtBu promoted intramolecular C-H arylation.
    Organic & biomolecular chemistry, 2016, Sep-28, Volume: 14, Issue:36

    A simple, efficient, rapid and transition metal-free methodology has been developed by utilizing vasicine (a natural product), as a catalyst for the synthesis of phenanthridinones and dihydrophenanthridines. The reaction proceeds through intramolecular C-H arylation with aryl halides in the presence of KOtBu as a base under microwave irradiation in sulfolane as a solvent. The reaction proceeds well with various aryl iodides, bromides and more remarkably with less reactive aryl chlorides for 15 minutes, providing the corresponding products in 45-90% yields.

    Topics: Alkaloids; Butanols; Microwaves; Molecular Structure; Phenanthrenes; Phenanthridines; Quinazolines

2016