terpestacin and cyclopentenone

terpestacin has been researched along with cyclopentenone* in 1 studies

Other Studies

1 other study(ies) available for terpestacin and cyclopentenone

Article	Year
Terpestacin core structure. control of stereochemistry. Organic letters, 2005, Oct-27, Volume: 7, Issue:22 [reaction: see text] The alpha-hydroxycyclopentenone core structure of terpestacin has been prepared in a model system through an allene ether Nazarov cyclization of an alkylidene-gamma-butyrolactone followed by regio- and stereoselective alkylation reactions. The stereochemistry at C15 (terpestacin numbering) has been used to control stereochemistry at C1 and at C23. The use of E-alkylidene-gamma-butyrolactones extends the scope of the cationic cyclopentannelation reaction. Topics: Alkylation; Bridged Bicyclo Compounds; Cyclopentanes; Molecular Structure; Stereoisomerism	2005

Article

Year

Terpestacin core structure. control of stereochemistry.

Organic letters, 2005, Oct-27, Volume: 7, Issue:22

[reaction: see text] The alpha-hydroxycyclopentenone core structure of terpestacin has been prepared in a model system through an allene ether Nazarov cyclization of an alkylidene-gamma-butyrolactone followed by regio- and stereoselective alkylation reactions. The stereochemistry at C15 (terpestacin numbering) has been used to control stereochemistry at C1 and at C23. The use of E-alkylidene-gamma-butyrolactones extends the scope of the cationic cyclopentannelation reaction.

Topics: Alkylation; Bridged Bicyclo Compounds; Cyclopentanes; Molecular Structure; Stereoisomerism

2005