tempo has been researched along with cyclopropane* in 1 studies
1 other study(ies) available for tempo and cyclopropane
| Article | Year |
|---|---|
Concerning the mechanism of the FeCl3-catalyzed alpha-oxyamination of aldehydes: evidence for a non-SOMO activation pathway.
The mechanism of a recently reported aldehyde alpha-oxyamination reaction has been studied using a combination of kinetic, spectrometric, and spectrophotometric techniques. Most crucially, the use of a validated cyclopropane-based radical-clock substrate has demonstrated that carbon-oxygen bond formation occurs predominantly through an enamine activation manifold. The mechanistic details reported herein indicate that, as has been proposed for previously studied alcohol oxidations, complexation between TEMPO and a simple metal salt leads to electrophilic ionic reactivity. Topics: Aldehydes; Amination; Catalysis; Chlorides; Cyclic N-Oxides; Cyclopropanes; Electrochemistry; Ferric Compounds; Isomerism; Oxygen; Solvents | 2010 |