tempo and cupric-chloride

tempo has been researched along with cupric-chloride* in 1 studies

Other Studies

1 other study(ies) available for tempo and cupric-chloride

Article	Year
Cu(II)-nitroxyl radicals as catalytic galactose oxidase mimics. Organic & biomolecular chemistry, 2003, Sep-21, Volume: 1, Issue:18 Results from Hammett correlation studies and primary kinetic isotope effects for the CuCl-TEMPO catalysed aerobic benzyl alcohol oxidations are inconsistent with an oxoammonium based mechanism. We postulate a copper-mediated dehydrogenation mechanism, in which TEMPO regenerates the active Cu(II)-species. This mechanism is analogous to that observed for Galactose Oxidase and mimics thereof. Topics: Alcohols; Antioxidants; Benzyl Alcohols; Catalysis; Chemistry, Organic; Copper; Cyclic N-Oxides; Galactose Oxidase; Hydrogen Peroxide; Kinetics; Models, Chemical; Nitrogen Oxides; Ultraviolet Rays	2003

Article

Year

Cu(II)-nitroxyl radicals as catalytic galactose oxidase mimics.

Organic & biomolecular chemistry, 2003, Sep-21, Volume: 1, Issue:18

Results from Hammett correlation studies and primary kinetic isotope effects for the CuCl-TEMPO catalysed aerobic benzyl alcohol oxidations are inconsistent with an oxoammonium based mechanism. We postulate a copper-mediated dehydrogenation mechanism, in which TEMPO regenerates the active Cu(II)-species. This mechanism is analogous to that observed for Galactose Oxidase and mimics thereof.

Topics: Alcohols; Antioxidants; Benzyl Alcohols; Catalysis; Chemistry, Organic; Copper; Cyclic N-Oxides; Galactose Oxidase; Hydrogen Peroxide; Kinetics; Models, Chemical; Nitrogen Oxides; Ultraviolet Rays

2003