tempo has been researched along with cupric-bromide* in 1 studies
1 other study(ies) available for tempo and cupric-bromide
Article | Year |
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Direct gem-difluoromethylenation of sp(3)-hybridized carbon center through copper-mediated radical/radical cross-coupling for the construction of a CH2-CF2 linkage.
Efficient direct gem-difluoromethylenation of an sp(3)-hybridized carbon center in benzyl bromides using benzo-1,3-azolic (oxa-, thia- or aza-) difluoromethyl bromides for construction of a CH2-CF2 linkage has been developed through radical/radical C-C cross-coupling via two separate single electron transfer processes (SET) under the promotion of different copper sources. Topics: Alkylation; Benzimidazoles; Benzothiazoles; Benzoxazoles; Benzyl Compounds; Bromides; Catalysis; Copper; Cyclic N-Oxides; Free Radicals; Hydrocarbons, Fluorinated; Oxidation-Reduction | 2015 |