tedanolide-c and 3-hydroxybutanal

tedanolide-c has been researched along with 3-hydroxybutanal* in 1 studies

Other Studies

1 other study(ies) available for tedanolide-c and 3-hydroxybutanal

Article	Year
A Kiyooka aldol approach for the synthesis of the C(14)-C(23) segment of the diastereomeric analog of tedanolide C. Organic letters, 2011, Nov-18, Volume: 13, Issue:22 The challenging synthesis of a quaternary center within the highly oxygenated setting of tedanolide C can be performed via a Kiyooka aldol reaction. Here, the diastereomeric analog of tedanolide C with the configurations between C10 and C20 opposite compared to the proposed structure was chosen as the synthetic target. The tetra-substituted silyl ketene acetal provides the southern hemisphere of tedanolide C in useful selectivities, and the absolute configuration of the newly generated quaternary center was determined by NOE experiments of the corresponding acetonide. Topics: Aldehydes; Carbon; Ketones; Macrolides; Molecular Structure; Stereoisomerism	2011

Article

Year

A Kiyooka aldol approach for the synthesis of the C(14)-C(23) segment of the diastereomeric analog of tedanolide C.

Organic letters, 2011, Nov-18, Volume: 13, Issue:22

The challenging synthesis of a quaternary center within the highly oxygenated setting of tedanolide C can be performed via a Kiyooka aldol reaction. Here, the diastereomeric analog of tedanolide C with the configurations between C10 and C20 opposite compared to the proposed structure was chosen as the synthetic target. The tetra-substituted silyl ketene acetal provides the southern hemisphere of tedanolide C in useful selectivities, and the absolute configuration of the newly generated quaternary center was determined by NOE experiments of the corresponding acetonide.

Topics: Aldehydes; Carbon; Ketones; Macrolides; Molecular Structure; Stereoisomerism

2011