tannins and resorcinol

Ferrihydrite (Fh) has been recently used in water treatment for removing dissolved organic matter (DOM), but its governing interactions with low-molecular weight DOM are largely unknown. This study aimed to elucidate the influence of chemical structure of DOM on the interactions between functional groups of DOM and Fh using various surrogates representing DOM in natural waters. We tested four surrogate compounds: L-glutamic acid, resorcinol, L-serine, and tannic acid, which represent the main chemical groups of carboxylic and hydroxyl groups; and the Suwannee River NOM (SRNOM) that represents the composition of DOM in natural aquatic systems. Batch adsorption experiments revealed that the DOM adsorption onto Fh was significantly influenced by the steric arrangements of -COOH and -OH functional groups. Both L-serine with α-carboxyl group and resorcinol with hydroxyl groups in meta-position were marginally removed by Fh, indicating that the adsorption of DOM on Fh was determined by their chemical structures and the relative positions of carboxylate and hydroxyl groups. The adsorption of L-glutamic acid was controlled by the pH-dependent ligand exchange of γ-carboxyl groups, which was similar to the SRNOM adsorption. In contrast, adsorption of tannic acid was not affected by pH, which can be explained by a two-step adsorption, namely, ligand exchange followed by multi-layer adsorption to the partitioning phase. The results of kinetic experiments demonstrated that adsorption of DOM by Fh was significant and rapid. The kinetic adsorption data can be expressed by the pseudo-second-order equation, indicating that the adsorption step might be the rate-limiting step.

Topics: Adsorption; Ferric Compounds; Glutamic Acid; Humic Substances; Kinetics; Models, Theoretical; Molecular Weight; Resorcinols; Rivers; Serine; Tannins; Water Pollutants, Chemical; Water Purification

The synthesis process of carbon xerogels is limited, mainly due to two drawbacks that prevent their introduction onto the market: (i) the long time required for producing the material and (ii) the reagents used for the synthesis, which are costly and harmful to the environment. Microwave radiation is expected to produce a reduction in time of more than 90%, while the use of tannin instead of resorcinol will probably result in a cost-effective carbonaceous material.. Resorcinol-tannin-formaldehyde xerogels containing different amounts of tannin, either with or without a surfactant (sodium dodecyl sulphate), were synthesized by means of two different heating methods: conventional and microwave heating. The effects of the surfactant, the heating method and the addition of tannin upon the porous structure and the chemical composition of the final materials were evaluated.. It was found that the addition of surfactant is essential for obtaining highly porous xerogels when using tannins. The heating method also plays an important role, as conventionally synthesized samples display a greater volume of large pores. However, tannins are less sensitive to microwave radiation and their use results in tannin-formaldehyde xerogels that have a porous structure and chemical composition similar to those of resorcinol-formaldehyde xerogels.

Topics: Acacia; Carbon; Formaldehyde; Gels; Heating; Hot Temperature; Hydrogen-Ion Concentration; Materials Testing; Microwaves; Porosity; Resorcinols; Sodium Dodecyl Sulfate; Spectroscopy, Fourier Transform Infrared; Surface-Active Agents; Tannins

The removal of small trihalomethane precursors (THMPs) from aqueous solution by two commercial nanofiltration membranes (NF70 and NF270) was investigated. Resorcinol, phloroglucinol, and 3-hydroxybenzoic acid were selected as model compounds of small THMPs, while tannic acid was chosen as a medium molecular disinfection by-product (DBP) precursor for comparison. The performance of nanofiltration membranes were evaluated by introducing polyethylene glycol (PEG) solutions and uncharged saccharides to estimate molecular weight cut-off (MWCO) and membrane pore radii, respectively. The streaming potential was measured to estimate the membrane surface charge at different pH values, which reveals that the NF270 membrane is more pH-sensitive than the NF70 membrane. The rejections of the above selected THMPs were assessed under various pH values, and the removal efficiencies of THMPs for both membranes at high pH values are reasonably well. Charge exclusion is the prevailing mechanism for the selected small model compounds retended by the negatively charged nanofiltration membranes, while size exclusion and adsorption are controlled mechanisms but not sufficient for the rejection of unionized small organic molecules. In general, the NF270 membrane exhibits the superior permeation rate value, which takes an advantage over the NF70 membrane from the aspect of energy conservation.

Topics: Filtration; Hydrogen-Ion Concentration; Hydroxybenzoates; Membranes, Artificial; Nanotechnology; Nylons; Phloroglucinol; Resorcinols; Solutions; Tannins; Trihalomethanes; Water Pollutants, Chemical; Water Purification

Resorcinol-tannin-formaldehyde copolymer resins (RTF) were prepared by using the bark extracts of Taiwan acacia (Acacia confusa) and China fir (Cunninghamia lanceolata) to substitute part of the resorcinol. From the results, the content of reactive phenolic materials in Taiwan acacia and China fir bark extracts were 51.6% and 46.5%, respectively. Aromatic compounds were the main components in the bark extracts showed by FT-IR analysis. The conventional synthesis condition used for RF resin was certainly not suitable for the RTF copolymer resin. It should be formed the novolak RF prepolymer by reacting the resorcinol with formaldehyde at the first stage, and then the bark extracts added and underwent the copolymerization reaction under acidic condition at the second-stage. The RTF copolymer resins prepared had cold-setting capability. They had higher viscosity, shorter gel time as compared with the RF resin. The RTF copolymer resins could be carried out the gluing application immediately after the hardener was added and had bonding strength the same as RF resin. But the RTF copolymer resins had worse stability and shorter shelf life than RF resin.

Topics: Acacia; Biopolymers; Cunninghamia; Formaldehyde; Plant Bark; Plant Extracts; Resins, Plant; Resorcinols; Spectroscopy, Fourier Transform Infrared; Taiwan; Tannins; Viscosity

This research is dedicated to determine the rejection ratios of disinfection by-products (DBPs) precursors including resorcinol, phloroglucinol, 3-hydroxybenzoic acid, and tannic acid solution in the presence of calcium by nanofiltration with NF70 membrane. The rejections of these model compounds also were studied at various compositions of a feed solution by changing pH and concentrations of model compounds. It was found that the model compound rejection and membrane permeability increase with pH due to the conformational transformation of ionizable molecules and electric interaction between the model compounds and NF70 membrane. The interactions of model compounds with calcium have no significant effect on model compounds retentions. Because of the complexation of calcium with model compounds, calcium rejection rises with the presence of model compounds and with an increase of pH.

Topics: Calcium; Disinfection; Equipment Design; Filtration; Hydrogen-Ion Concentration; Hydroxybenzoates; Ions; Models, Chemical; Nanotechnology; Phloroglucinol; Resorcinols; Tannins; Temperature; Waste Disposal, Fluid; Water Purification