spirolide-c and 3-hydroxybutanal

spirolide-c has been researched along with 3-hydroxybutanal* in 1 studies

Other Studies

1 other study(ies) available for spirolide-c and 3-hydroxybutanal

Article	Year
Studies toward the synthesis of spirolides: assembly of the elaborated E-ring fragment. Organic letters, 2009, Feb-19, Volume: 11, Issue:4 A stereoselective synthesis of the spiroimine fragment of spirolide C is described. The congested C7 and C29 tertiary and quaternary centers are constructed by a diastereoselective Ireland-Claisen rearrangement. The E ring is completed by means of an aldol cyclocondensation. Additional studies were preformed on the advanced intermediate to probe a future coupling strategy. Topics: Aldehydes; Catalysis; Lithium; Molecular Structure; Spiro Compounds; Stereoisomerism	2009

Article

Year

Studies toward the synthesis of spirolides: assembly of the elaborated E-ring fragment.

Organic letters, 2009, Feb-19, Volume: 11, Issue:4

A stereoselective synthesis of the spiroimine fragment of spirolide C is described. The congested C7 and C29 tertiary and quaternary centers are constructed by a diastereoselective Ireland-Claisen rearrangement. The E ring is completed by means of an aldol cyclocondensation. Additional studies were preformed on the advanced intermediate to probe a future coupling strategy.

Topics: Aldehydes; Catalysis; Lithium; Molecular Structure; Spiro Compounds; Stereoisomerism

2009