sorbicillinol has been researched along with ethyl-vinyl-ether* in 1 studies
1 other study(ies) available for sorbicillinol and ethyl-vinyl-ether
Article | Year |
---|---|
Establishing the True Structure of the Sorbicillinoid-Derived Isolate Rezishanone C by Total Synthesis.
The enantiomer, ent-4, of the true structure, 4, of the sorbicillinoid rezishanone C (sorbivinetone) has been synthesized from a homochiral cis-1,2-dihydrocatechol that is itself generated through the whole-cell biotransformation of toluene. These studies together with dispersion-corrected DFT calculations support the proposal that rezishanone C is an artefact of the isolation process and arises through a Diels-Alder reaction between ethyl vinyl ether and sorbicillinol (3). Topics: Cycloaddition Reaction; Cyclohexanones; Ethyl Ethers; Heterocyclic Compounds, 4 or More Rings; Molecular Structure; Quantum Theory; Stereoisomerism | 2017 |