sodium-perchlorate has been researched along with salophen* in 1 studies
1 other study(ies) available for sodium-perchlorate and salophen
| Article | Year |
|---|---|
Mixed-ligand Ru(II) complexes with 2,2'-bipyridine and tetradentate Schiff bases auxiliary ligands: Synthesis, physico-chemical study, DFT analysis, electrochemical and Na+ binding properties.
cis-Bis(2,2'-bipyridyl)dichlororuthenium(II)dihydrate complexed with Schiff bases salen (L1H2) and salophen (L2H2) provides complexes of compositions [Ru(L1)(bpy)2] 1 and [Ru(L2)(bpy)2] 2, respectively with cavity. The structure of these complexes characterized by spectroscopic studies were supported by their optimized geometries based on DFT calculations. Complexes 1 and 2 were then allowed to interact with methanolic solution of sodium perchlorate separately providing corresponding complexes 3 and 4 with the compositions 1.NaClO4 and 2.NaClO4, respectively. The formation constants were then evaluated by monitoring the changes in their UV-visible spectral features upon addition of different amount of sodium salts in the presence of a fixed concentration of the ruthenium complexes at a wavelength 294 nm. Emission (solution), luminescence microscopic and cyclic voltammetric studies of these complexes have also been made. Topics: 2,2'-Dipyridyl; Chelating Agents; Chemical Phenomena; Chemistry, Physical; Dimethyl Sulfoxide; Electrochemistry; Ethylenediamines; Ligands; Methanol; Molecular Structure; Perchlorates; Ruthenium; Salicylates; Schiff Bases; Sodium; Sodium Compounds; Solutions; Spectrophotometry, Ultraviolet | 2008 |