sodium-nitrite and 2-4-6-trichlorophenol

Oxidative degradation of p-nitrophenol (PNP) was investigated with NaNO(2) as the catalyst and dioxygen as the oxidizing agent in the presence of trichlorophenol (TCP). Although degradation of PNP alone was proved to be inefficient toward the NaNO(2)-mediated oxidative degradation system, when PNP in combination with TCP was used as the substrate, NaNO(2) showed relatively high catalytic activity for eradicating both PNP and TCP with molecular oxygen. Reaction conditions to the degradation system, e.g., temperatures, reaction time, pH, NaNO(2) and TCP concentrations were optimized. PNP could be highly efficiently degraded in the NaNO(2)/TCP/O(2) system (more than 99% removal for PNP) and the TOC removal of the mixture of PNP and TCP could reach 71% at 150 degrees C, 0.5 MPa oxygen pressure. Degradation products were determined, and 93% carbon atom was clarified. A plausible overall mechanism for the formation of active species is described, in which peroxylnitrite was believed to be a dominating active intermediate being responsible for destroying the substrates, PNP and TCP. The novel NaNO(2)-based concurrent oxidation system for PNP and TCP provides a potential application in treatment of multi-component industrial effluents.

Topics: Catalysis; Chlorophenols; Hydrogen-Ion Concentration; Models, Chemical; Molecular Structure; Nitrophenols; Oxygen; Sodium Nitrite