sodium-hypochlorite and sulfuric-acid

Topics: Acids; Antineoplastic Agents; Carcinogens; Chemical Phenomena; Chemistry; Cisplatin; Cyclophosphamide; Daunorubicin; Ditiocarb; Doxorubicin; Hydrobromic Acid; Hydrolysis; Ifosfamide; Lomustine; Mercaptopurine; Methods; Methotrexate; Oxidation-Reduction; Potassium Permanganate; Sodium Hypochlorite; Streptozocin; Sulfuric Acids; Thioguanine; Vinblastine; Vincristine; Waste Products; Zinc

A novel hydrometallurgical process was proposed for selective recovery of Cu, Ag, Au and Pd from waste printed circuit boards (PCBs). More than 99% of copper content was dissolved by using two consecutive sulfuric acid leaching steps in the presence of H2O2 as oxidizing agents. The solid residue of 2nd leaching step was treated by acidic thiourea in the presence of ferric iron as oxidizing agent and 85.76% Au and 71.36% Ag dissolution was achieved. The precipitation of Au and Ag from acidic thiourea leachate was investigated by using different amounts of sodium borohydride (SBH) as a reducing agent. The leaching of Pd and remained gold from the solid reside of 3rd leaching step was performed in NaClO-HCl-H2O2 leaching system and the effect of different parameters was investigated. The leaching of Pd and specially Au increased by increasing the NaClO concentration up to 10V% and any further increasing the NaClO concentration has a negligible effect. The leaching of Pd and Au increased by increasing the HCl concentration from 2.5 to 5M. The leaching of Pd and Au were endothermic and raising the temperature had a positive effect on leaching efficiency. The kinetics of Pd leaching was quite fast and after 30min complete leaching of Pd was achieved, while the leaching of Au need a longer contact time. The best conditions for leaching of Pd and Au in NaClO-HCl-H2O2 leaching system were determined to be 5M HCl, 1V% H2O2, 10V% NaClO at 336K for 3h with a solid/liquid ratio of 1/10. 100% of Pd and Au of what was in the chloride leachate were precipitated by using 2g/L SBH. Finally, a process flow sheet for the recovery of Cu, Ag, Au and Pd from PCB was proposed.

Topics: Algorithms; Borohydrides; Chemical Precipitation; Copper; Electronic Waste; Gold; Hydrochloric Acid; Hydrogen Peroxide; Palladium; Sodium Hypochlorite; Sulfuric Acids; Thiourea

This research investigates the effects of household chemicals on human tissues. Five different human tissues (bone, tooth, hair, fingernails, and skin/muscle/fat) were immersed into six different corrosive agents. These agents consisted of hydrochloric acid, sulfuric acid, lye, bleach, organic septic cleaner, and Coca-Cola(®) soda. Tap water was used as a control. Tissue samples were cut to consistent sizes and submerged in the corrosive liquids. Over time, the appearance, consistency, and weight were documented. Hydrochloric acid was the most destructive agent in this study, consuming most tissues within 24 h. Sulfuric acid was the second most destructive agent in this study. Bleach, lye, and cola had no structural effects on the hard tissues of the body, but did alter the appearance or integrity of the hair, nails, or flesh in some way. The organic septic cleaner and tap water had no effect on any of the human tissue tested during the timeframe of the study.

Topics: Adipose Tissue; Carbonated Beverages; Caustics; Connective Tissue; Detergents; Femur; Forensic Pathology; Hair; Humans; Hydrochloric Acid; Incisor; Lye; Male; Middle Aged; Molar; Muscle, Skeletal; Nails; Skin; Sodium Hypochlorite; Sulfuric Acids; Time Factors

This paper concerns the morphology of hemp woody core cells, investigated by optical and scanning electron microscopy, and the chemical analysis of the hemp cells. Steam explosion was investigated as a pre-treatment step for woody hemp 'chènevotte', with the aim of optimizing the separation and delignification of woody fibres. In this study, we report the results of five experiments performed on 'chènevotte' samples impregnated in acid solution (0.1% w/w H2SO4) and steamed at 200, 210, 220, 230 and 240 degrees C for 180 s. The effect of process temperatures on the woody hemp core after acidic impregnation was followed by optical and scanning electron microscopy, by assessment of the chemical composition, and by evolution of the average degree of polymerization (DPv) values of the purified wood fibres. We found that treatment at 200 and 210 degrees C led to samples that were difficult to delignigy because the destructuring and disintegration of lignocellulosic materials were insufficient. A temperature of the order of 220-230 degrees C is required to obtain well-separated fibres. However, at a temperature of 240 degrees C, degradation and fibre damage were noted.

Topics: Carbohydrates; Cellulose; Lignin; Microscopy, Electron, Scanning; Plant Stems; Polymers; Polysaccharides; Sodium Hydroxide; Sodium Hypochlorite; Solubility; Steam; Sulfuric Acids; Temperature