silicon and phenylglyoxylic-acid

silicon has been researched along with phenylglyoxylic-acid* in 1 studies

Other Studies

1 other study(ies) available for silicon and phenylglyoxylic-acid

Article	Year
Synthesis and fungicidal activity of enantiomerically pure (R)- and (S)-silicon-containing azole fungicides. Bioorganic & medicinal chemistry, 2004, Jul-01, Volume: 12, Issue:13 Enantiomerically pure (R)- and (S)-1-(1H-1,2,4-triazol-1-yl)-2-(4-fluorophenyl)-3-trimethylsilylpropan-2-ol 1 were prepared via an enantioselective Grignard reaction. The absolute stereochemistry of 1 was determined by X-ray analysis. In a comparison of in vitro antifungal activities of the enantiomers, the (-)-enantiomer with the R-absolute configuration was far more potent than the (+)-enantiomer. Topics: Antifungal Agents; Azoles; Crystallography, X-Ray; Glyoxylates; Inhibitory Concentration 50; Mandelic Acids; Models, Molecular; Molecular Conformation; Molecular Structure; Oryza; Plant Diseases; Propanols; Rhizoctonia; Silicon; Stereoisomerism; Trimethylsilyl Compounds	2004

Article

Year

Synthesis and fungicidal activity of enantiomerically pure (R)- and (S)-silicon-containing azole fungicides.

Bioorganic & medicinal chemistry, 2004, Jul-01, Volume: 12, Issue:13

Enantiomerically pure (R)- and (S)-1-(1H-1,2,4-triazol-1-yl)-2-(4-fluorophenyl)-3-trimethylsilylpropan-2-ol 1 were prepared via an enantioselective Grignard reaction. The absolute stereochemistry of 1 was determined by X-ray analysis. In a comparison of in vitro antifungal activities of the enantiomers, the (-)-enantiomer with the R-absolute configuration was far more potent than the (+)-enantiomer.

Topics: Antifungal Agents; Azoles; Crystallography, X-Ray; Glyoxylates; Inhibitory Concentration 50; Mandelic Acids; Models, Molecular; Molecular Conformation; Molecular Structure; Oryza; Plant Diseases; Propanols; Rhizoctonia; Silicon; Stereoisomerism; Trimethylsilyl Compounds

2004