silicon and 3-buten-2-one

silicon has been researched along with 3-buten-2-one* in 1 studies

Other Studies

1 other study(ies) available for silicon and 3-buten-2-one

Article	Year
Regioselective silylphosphination of methyl vinyl ketone with complexes containing cyclic and linear iron-silicon-phosphorus reacting sites. Chemical communications (Cambridge, England), 2005, Feb-21, Issue:7 Treatment of Cp(CO)Fe{kappa2(Si,P)-SiMe2PPh2} with methyl vinyl ketone gave a 1,2-addition product, Cp(CO)Fe{kappa2(Si,P)-SiMe2OCMe(CH=CH2)PPh2}. A linear-type Cp(CO)2FeSiMe2PPh2 also reacted with the ketone to yield a 1,4-addition product, Cp(CO)2Fe{kappa1(Si)-SiMe2OC(Me=CHCH2PPh2}, which was further converted to a seven-membered metallacycle, Cp*(CO)Fe{kappa2(Si,P)-SiMe2OC(Me)=CHCH2PPh2}, upon photolysis. Topics: Butanones; Crystallography, X-Ray; Cyclization; Iron; Light; Magnetic Resonance Spectroscopy; Models, Molecular; Organometallic Compounds; Phosphorus; Sensitivity and Specificity; Silicon; Stereoisomerism	2005

Article

Year

Regioselective silylphosphination of methyl vinyl ketone with complexes containing cyclic and linear iron-silicon-phosphorus reacting sites.

Chemical communications (Cambridge, England), 2005, Feb-21, Issue:7

Treatment of Cp*(CO)Fe{kappa2(Si,P)-SiMe2PPh2} with methyl vinyl ketone gave a 1,2-addition product, Cp*(CO)Fe{kappa2(Si,P)-SiMe2OCMe(CH=CH2)PPh2}. A linear-type Cp*(CO)2FeSiMe2PPh2 also reacted with the ketone to yield a 1,4-addition product, Cp*(CO)2Fe{kappa1(Si)-SiMe2OC(Me=CHCH2PPh2}, which was further converted to a seven-membered metallacycle, Cp*(CO)Fe{kappa2(Si,P)-SiMe2OC(Me)=CHCH2PPh2}, upon photolysis.

Topics: Butanones; Crystallography, X-Ray; Cyclization; Iron; Light; Magnetic Resonance Spectroscopy; Models, Molecular; Organometallic Compounds; Phosphorus; Sensitivity and Specificity; Silicon; Stereoisomerism

2005