silicon and (trifluoromethyl)-trimethylsilane

silicon has been researched along with (trifluoromethyl)-trimethylsilane* in 1 studies

Other Studies

1 other study(ies) available for silicon and (trifluoromethyl)-trimethylsilane

Article	Year
Gas phase structure of Ruppert's reagent, CF3SiMe3. The journal of physical chemistry. A, 2005, Sep-22, Volume: 109, Issue:37 CF3SiMe3 (Ruppert's reagent) has been investigated by gas phase electron diffraction, microwave spectroscopy and quantum chemical methods, deriving structural parameters and the barrier height for the methyl torsion. The bond length of the Si-CF3 bond, 1.941(3) A, is the longest Si-C bond observed so far in the gas phase. The V3 barrier for the methyl group torsion (V3= 5.71 kJ/mol) is only slightly lower than barriers determined for other trimethylsilane compounds. Topics: Fluorine; Gases; Hydrocarbons, Fluorinated; Indicators and Reagents; Microwaves; Models, Molecular; Molecular Conformation; Quantum Theory; Silicon; Spectrum Analysis; Trimethylsilyl Compounds	2005

Article

Year

Gas phase structure of Ruppert's reagent, CF3SiMe3.

The journal of physical chemistry. A, 2005, Sep-22, Volume: 109, Issue:37

CF3SiMe3 (Ruppert's reagent) has been investigated by gas phase electron diffraction, microwave spectroscopy and quantum chemical methods, deriving structural parameters and the barrier height for the methyl torsion. The bond length of the Si-CF3 bond, 1.941(3) A, is the longest Si-C bond observed so far in the gas phase. The V3 barrier for the methyl group torsion (V3= 5.71 kJ/mol) is only slightly lower than barriers determined for other trimethylsilane compounds.

Topics: Fluorine; Gases; Hydrocarbons, Fluorinated; Indicators and Reagents; Microwaves; Models, Molecular; Molecular Conformation; Quantum Theory; Silicon; Spectrum Analysis; Trimethylsilyl Compounds

2005