selectfluor and propadiene

selectfluor has been researched along with propadiene* in 1 studies

Other Studies

1 other study(ies) available for selectfluor and propadiene

ArticleYear
An efficient approach for monofluorination via highly regioselective fluorohydroxylation reaction of 3-aryl-1,2-allenes with Selectfluor.
    Organic letters, 2008, Feb-21, Volume: 10, Issue:4

    The internal C-C double bond in 3-aryl-1,2-allenes was highly regioselectively fluorohydroxylated to afford 2-fluoroalken-3-ols in 37-88% yields by using Selectfluor as the electrophilic reagent. The regioselectivity may be determined by the electronic effect, while the reactivity may be controlled by the stabilization effect of the aryl group in the allylic cationic intermediates.

    Topics: Alkadienes; Catalysis; Cyclization; Diazonium Compounds; Fluorine; Hydroxylation; Molecular Structure; Stereoisomerism

2008