selectfluor has been researched along with carbene* in 1 studies
1 other study(ies) available for selectfluor and carbene
Article | Year |
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Synthesis and Suzuki Reactions of N-Heterocyclic Carbene Difluoro(aryl)-boranes.
Readily available NHC-arylboranes (NHC-BH2Ar) are converted in high yield to stable NHC-difluoro(aryl)boranes (NHC-BF2Ar) by treatment with 2 equiv of 1-chloromethyl-4-fluoro-1,4-diazonia-bicyclo[2.2.2]octane bis(tetrafluoroborate) (Selectfluor). In turn, the NHC-difluoro(aryl)boranes participate directly in Suzuki reactions under conditions previously used for anionic trifluoroborate salts. Accordingly, NHC-difluoroboranes are a new class of stable precursors for Suzuki reactions. Topics: Boranes; Catalysis; Diazonium Compounds; Heterocyclic Compounds; Methane; Molecular Structure; Palladium | 2015 |