selectfluor and carbene

selectfluor has been researched along with carbene* in 1 studies

Other Studies

1 other study(ies) available for selectfluor and carbene

Article	Year
Synthesis and Suzuki Reactions of N-Heterocyclic Carbene Difluoro(aryl)-boranes. Organic letters, 2015, Jul-17, Volume: 17, Issue:14 Readily available NHC-arylboranes (NHC-BH2Ar) are converted in high yield to stable NHC-difluoro(aryl)boranes (NHC-BF2Ar) by treatment with 2 equiv of 1-chloromethyl-4-fluoro-1,4-diazonia-bicyclo[2.2.2]octane bis(tetrafluoroborate) (Selectfluor). In turn, the NHC-difluoro(aryl)boranes participate directly in Suzuki reactions under conditions previously used for anionic trifluoroborate salts. Accordingly, NHC-difluoroboranes are a new class of stable precursors for Suzuki reactions. Topics: Boranes; Catalysis; Diazonium Compounds; Heterocyclic Compounds; Methane; Molecular Structure; Palladium	2015

Article

Year

Synthesis and Suzuki Reactions of N-Heterocyclic Carbene Difluoro(aryl)-boranes.

Organic letters, 2015, Jul-17, Volume: 17, Issue:14

Readily available NHC-arylboranes (NHC-BH2Ar) are converted in high yield to stable NHC-difluoro(aryl)boranes (NHC-BF2Ar) by treatment with 2 equiv of 1-chloromethyl-4-fluoro-1,4-diazonia-bicyclo[2.2.2]octane bis(tetrafluoroborate) (Selectfluor). In turn, the NHC-difluoro(aryl)boranes participate directly in Suzuki reactions under conditions previously used for anionic trifluoroborate salts. Accordingly, NHC-difluoroboranes are a new class of stable precursors for Suzuki reactions.

Topics: Boranes; Catalysis; Diazonium Compounds; Heterocyclic Compounds; Methane; Molecular Structure; Palladium

2015