scandium-triflate has been researched along with ethylene* in 1 studies
1 other study(ies) available for scandium-triflate and ethylene
Article | Year |
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Highly diastereoselective synthesis of beta-carboxy-gamma-lactams and their ethyl esters via Sc(OTf)(3)-catalyzed imino Mukaiyama-aldol type reaction of 2,5-bis(trimethylsilyloxy)furan with imines.
Functionalized gamma-lactams are found to be crucial intermediates in the synthesis of biologically important natural products. We herein described a highly diastereoselective synthesis of beta-carboxy-gamma-lactams and their ethyl ester derivatives, in high yields with high diastereomeric ratio, via the Mukaiyama-aldol type reaction of 2,5-bis(trimethysilyloxy)furan with imines, employing Sc(OTf)(3) as a catalyst. Topics: Carboxylic Acids; Catalysis; Esters; Ethylenes; Furans; Imines; Lactams; Mesylates; Molecular Structure; Scandium; Stereoisomerism; Trimethylsilyl Compounds | 2007 |