scandium-triflate and benzoyl-chloride

scandium-triflate has been researched along with benzoyl-chloride* in 1 studies

Other Studies

1 other study(ies) available for scandium-triflate and benzoyl-chloride

Article	Year
First catalytic and green synthesis of aryl-(Z)-vinyl chlorides and its plausible addition-elimination mechanism. Organic letters, 2007, Mar-15, Volume: 9, Issue:6 Via a catalytic cycle in the presence of scandium triflate (2 mol %)/DMF (1 mol %)/benzoyl chloride (5 mol %), aromatic ketones were treated with bis(trichloromethyl) carbonate (BTC) to afford aryl-(Z)-vinyl chlorides. All metal triflates tested in the reaction showed highly catalytic activity. A plausible addition-elimination mechanism was proposed. The present work describes the first catalytic and green route to the synthesis of aryl-(Z)-vinyl chlorides. [reaction: see text] Topics: Benzoates; Catalysis; Crystallography, X-Ray; Dimethylformamide; Ketones; Mesylates; Organometallic Compounds; Scandium; Vinyl Chloride; Vinyl Compounds	2007

Article

Year

First catalytic and green synthesis of aryl-(Z)-vinyl chlorides and its plausible addition-elimination mechanism.

Organic letters, 2007, Mar-15, Volume: 9, Issue:6

Via a catalytic cycle in the presence of scandium triflate (2 mol %)/DMF (1 mol %)/benzoyl chloride (5 mol %), aromatic ketones were treated with bis(trichloromethyl) carbonate (BTC) to afford aryl-(Z)-vinyl chlorides. All metal triflates tested in the reaction showed highly catalytic activity. A plausible addition-elimination mechanism was proposed. The present work describes the first catalytic and green route to the synthesis of aryl-(Z)-vinyl chlorides. [reaction: see text]

Topics: Benzoates; Catalysis; Crystallography, X-Ray; Dimethylformamide; Ketones; Mesylates; Organometallic Compounds; Scandium; Vinyl Chloride; Vinyl Compounds

2007