scandium-triflate and acetic-anhydride

scandium-triflate has been researched along with acetic-anhydride* in 1 studies

Other Studies

1 other study(ies) available for scandium-triflate and acetic-anhydride

Article	Year
Scandium(III) trifluoromethanesulfonate catalyzed aromatic nitration with inorganic nitrates and acetic anhydride. Chemical & pharmaceutical bulletin, 2002, Volume: 50, Issue:8 The rare earth metal(III) trifluoromethanesulfonate (rare earth metal(III) triflate, RE(OTf)3) was found to be an efficient catalyst for aromatic nitration with carboxylic anhydride-inorganic nitrate as the nitrating agent. In the presence of a catalytic amount of RE(OTf)3, the nitration of substituted benzenes proceeded to afford the corresponding nitrobenzenes. Especially, scandium(III) trifluoromethanesulfonate (scandium(III) triflate, Sc(OTf)3) is the most active catalyst among our tested Lewis acids. It was also found that acetic anhydride-Al(NO3).9H2O is the most active nitrating agent in this system. Topics: Acetic Anhydrides; Mesylates; Nitrates; Scandium	2002

Article

Year

Scandium(III) trifluoromethanesulfonate catalyzed aromatic nitration with inorganic nitrates and acetic anhydride.

Chemical & pharmaceutical bulletin, 2002, Volume: 50, Issue:8

The rare earth metal(III) trifluoromethanesulfonate (rare earth metal(III) triflate, RE(OTf)3) was found to be an efficient catalyst for aromatic nitration with carboxylic anhydride-inorganic nitrate as the nitrating agent. In the presence of a catalytic amount of RE(OTf)3, the nitration of substituted benzenes proceeded to afford the corresponding nitrobenzenes. Especially, scandium(III) trifluoromethanesulfonate (scandium(III) triflate, Sc(OTf)3) is the most active catalyst among our tested Lewis acids. It was also found that acetic anhydride-Al(NO3).9H2O is the most active nitrating agent in this system.

Topics: Acetic Anhydrides; Mesylates; Nitrates; Scandium

2002