sambucinol and mevalonolactone

sambucinol has been researched along with mevalonolactone* in 1 studies

Other Studies

1 other study(ies) available for sambucinol and mevalonolactone

Article	Year
Structure determination and biosynthesis of a novel metabolite of Fusarium culmorum, apotrichodiol. The Journal of biological chemistry, 1987, Nov-15, Volume: 262, Issue:32 A novel dead-end metabolite of Fusarium culmorum was isolated and characterized (Zamir, L. O., and Devor, K. A. (1987) J. Biol. Chem. 15348-15353). This 3 alpha, 13-dihydroxy-apotrichothec-9-ene is herein given the trivial name of apotrichodiol to indicate its basic structure. The characterization of apotrichodiol was established through the application of spectroscopic techniques (ultraviolet, 1H-NMR, 13C-NMR, COSY, and DEPT experiments) on the natural product as well as on its diacetate derivative. The mode of folding of its precursor farnesyl pyrophosphate was derived from feeding experiments with 3,4-[13C2]mevalonolactone. 13C-NMR assignments were also made of 3-acetyldeoxynivalenol and sambucinol which were derived from these feedings with enriched mevalonolactone. Topics: Chromatography, High Pressure Liquid; Fusarium; Magnetic Resonance Spectroscopy; Mevalonic Acid; Sesquiterpenes; Trichothecenes	1987

Article

Year

Structure determination and biosynthesis of a novel metabolite of Fusarium culmorum, apotrichodiol.

The Journal of biological chemistry, 1987, Nov-15, Volume: 262, Issue:32

A novel dead-end metabolite of Fusarium culmorum was isolated and characterized (Zamir, L. O., and Devor, K. A. (1987) J. Biol. Chem. 15348-15353). This 3 alpha, 13-dihydroxy-apotrichothec-9-ene is herein given the trivial name of apotrichodiol to indicate its basic structure. The characterization of apotrichodiol was established through the application of spectroscopic techniques (ultraviolet, 1H-NMR, 13C-NMR, COSY, and DEPT experiments) on the natural product as well as on its diacetate derivative. The mode of folding of its precursor farnesyl pyrophosphate was derived from feeding experiments with 3,4-[13C2]mevalonolactone. 13C-NMR assignments were also made of 3-acetyldeoxynivalenol and sambucinol which were derived from these feedings with enriched mevalonolactone.

Topics: Chromatography, High Pressure Liquid; Fusarium; Magnetic Resonance Spectroscopy; Mevalonic Acid; Sesquiterpenes; Trichothecenes

1987