samarium and iodine
samarium has been researched along with iodine in 154 studies
Research
Studies (154)
| Timeframe | Studies, this research(%) | All Research% |
|---|---|---|
| pre-1990 | 1 (0.65) | 18.7374 |
| 1990's | 1 (0.65) | 18.2507 |
| 2000's | 79 (51.30) | 29.6817 |
| 2010's | 65 (42.21) | 24.3611 |
| 2020's | 8 (5.19) | 2.80 |
Authors
| Authors | Studies |
|---|---|
| Hobbs, BB; Taylor, KW; Villagran, JE | 1 |
| Miyawaki, K; Morikawa, H; Suzuki, H | 1 |
| Berliner, MA; Clark, MP; Nag, PP; Stroup, BW; Williams, DR | 1 |
| Ichikawa, S; Matsuda, A; Shuto, S | 1 |
| McAuley, BJ; Nieuwenhuyzen, M; Sheldrake, GN | 1 |
| Keck, GE; Wager, CA | 1 |
| Aoyagi, Y; Ohta, A | 1 |
| Kawasaki, I; Nagamine, R; Nakamura, S; Ohta, S; Okuyama, K; Tsujita, T; Yamashita, M | 1 |
| Kono, K; Kunishima, M; Nakata, D; Sakuma, T; Sato, S; Tani, S | 1 |
| Brown, GA; Le Huérou, Y; Molander, GA | 1 |
| Concellón, JM; Rodríguez-Solla, H | 2 |
| Hazell, R; Jacobsen, MF; Skrydstrup, T; Turks, M | 1 |
| Brown, GA; Molander, GA; Storch de Gracia, I | 1 |
| Molander, GA; St Jean, DJ | 1 |
| Flowers, RA; Prasad, E | 1 |
| Keck, GE; Truong, AP | 1 |
| Chiara, JL; Sesmilo, E | 1 |
| Ichikawa, S; Kodama, T; Matsuda, A; Shuto, S | 1 |
| Riber, D; Skrydstrup, T | 1 |
| Curran, DP; Nagashima, T; Rivkin, A | 1 |
| Dahlén, A; Hilmersson, G | 1 |
| Mikkelsen, LM; Skrydstrup, T | 1 |
| Blakskaer, P; Høj, B; Riber, D; Skrydstrup, T | 1 |
| Bheema Rao, P; Chen, DY; Hao, J; Huang, X; Nicolaou, KC; Rassias, G; Reddy, MV; Snyder, SA | 1 |
| Cabrera, A; Le Lagadec, R; Miranda, R; Pérez-Flores, J; Rubio, L; Velasco, L | 1 |
| Beau, JM; Palmier, S; Vauzeilles, B | 1 |
| Sono, M | 1 |
| Fujii, N; Oishi, S; Otaka, A; Sasaki, Y; Tamamura, H; Watanabe, J; Yukimasa, A | 1 |
| Dahlén, A; Hilmersson, G; Lahmann, M; Oscarson, S; Sundgren, A | 1 |
| Bardales, E; Concellón, JM | 1 |
| George, KM; Molander, GA; Monovich, LG | 1 |
| Ding, H; Friestad, GK | 1 |
| Fujii, N; Kinoshita, T; Oishi, S; Otaka, A; Sasaki, Y; Tamamura, H; Watanabe, H; Watanabe, J; Yukimasa, A | 1 |
| Ichikawa, S; Matsuda, A | 2 |
| Bardales, E; Bernad, PL; Concellón, JM | 1 |
| Edmonds, DJ; Johnston, D; Procter, DJ | 1 |
| Davies, SG; Garner, AC; Rodríguez-Solla, H; Smith, AD; Tamayo, JA | 1 |
| Cho, MS; Kang, SH; Kim, YH; Lee, IS | 1 |
| Honda, T; Namiki, H; Takahashi, R | 1 |
| Feng, CG; Huang, PQ; Ye, JL; Zheng, X | 1 |
| Desvergnes, S; Py, S; Vallée, Y | 1 |
| Cormier, EP; Molander, GA | 1 |
| Concellon, C; Cowley, AR; Davies, SG; Garner, AC; Parkes, AL; Rodriguez-Solla, H; Smith, AD; Tamayo, JA | 1 |
| Blann, K; Caddy, J; Williams, DB | 1 |
| Chiara, JL; Cristóbal-Lumbroso, G; García, A | 1 |
| McKerlie, F; Procter, DJ; Rudkin, IM; Wynne, G | 1 |
| Kamochi, Y; Kudo, T; Masuda, T; Takadate, A | 1 |
| Ebran, JP; Hazell, RG; Skrydstrup, T | 1 |
| Gu, Q; Li, YC; Zheng, YH | 1 |
| Linhardt, RJ; Yuan, X | 1 |
| Matthews, BW; Mooers, BH | 1 |
| Dahlén, A; Hilmersson, G; Nilsson, A | 1 |
| Liu, YK; Xu, DQ; Xu, ZY; Zhang, YM; Zheng, H | 1 |
| Ichikawa, S | 3 |
| Brand, S; McAllister, LA; Procter, DJ; Stefaniak, M; Turner, KL | 1 |
| Ebran, JP; Jensen, CM; Johannesen, SA; Karaffa, J; Lindsay, KB; Skrydstrup, T; Taaning, R | 1 |
| Edmonds, DJ; Li, A; Nicolaou, KC | 1 |
| Donadel, OJ; Martín, T; Martín, VS; Padrón, JM | 1 |
| Bennasar, ML; Christensen, KL; Ferrando, F; Lindsay, KB; Overgaard, J; Roca, T; Skrydstrup, T | 1 |
| Aulenta, F; Berndt, M; Brüdgam, I; Hartl, H; Reissig, HU; Sörgel, S | 1 |
| Choi, SY; Chung, YK; Jung, JH; Kim, MA; Kim, TR; Kim, YW; Lee, E; Shin, S | 1 |
| Christensen, KL; Lindsay, KB; Mittag, T; Nielsen, NC; Skrydstrup, T | 1 |
| Paquette, LA; Wah Lai, K | 1 |
| Lowe, JT; Panek, JS | 1 |
| Eguchi, T; Iwasaki, H; Ohno, H; Tanaka, T; Tsutsui, N | 1 |
| Concellón, JM; Paz, NR; Rodríguez-Solla, H; Santos, D; Simal, C | 1 |
| Farran, H; Hoz, S | 1 |
| Aranishi, E; Honda, T; Kaneda, K | 1 |
| Collins, KD; De Grazia, S; Guazzelli, G; Matsubara, H; Procter, DJ; Spain, M | 1 |
| Huang, PQ; Ruan, YP; Wu, SF; Zheng, X | 1 |
| Lentz, D; Reissig, HU; Saadi, J | 1 |
| Chen, JS; Ellery, SP; Nicolaou, KC | 1 |
| Cheng, B; Xu, Q; Ye, X; Zhai, H | 1 |
| Masson, G; Py, S; Vallée, Y | 1 |
| Bradley, PA; Duffy, LA; Flowers, RA; Matsubara, H; Parmar, D; Procter, DJ; Sadasivam, DV | 1 |
| Beemelmanns, C; Reissig, HU | 5 |
| Huang, PQ; Ruan, YP; Wang, XW; Xiang, YG; Zheng, X | 1 |
| Begtrup, M; Kristensen, JL; Nielsen, SD; Smith, G | 1 |
| Arseniyadis, S; Dagneau, P; Faraoni, R; Jennings, MP; Lanver, A; Lizos, DE; Nicolaou, KC; Ortiz, A; Zhang, H | 1 |
| Nakata, T | 2 |
| Collins, KD; De Grazia, S; Guazzelli, G; Helliwell, M; Matsubara, H; Oliveira, JM; Procter, DJ; Sautier, B | 1 |
| Concellón, C; Concellón, JM; del Amo, V; Rodríguez-Solla, H | 1 |
| Ankner, T; Hilmersson, G; Wettergren, J | 1 |
| Bowker, S; Campbell, L; Collins, KD; Garcia Altur, JV; Harb, HY; Procter, DJ | 1 |
| Bradley, PA; Matsubara, H; Parmar, D; Price, K; Procter, DJ; Spain, M | 1 |
| Li, CC; Xu, T; Yang, Z | 1 |
| Huang, PQ; Liu, XK; Qiu, S; Ruan, YP; Xiang, YG; Zheng, X | 1 |
| Coote, SC; Procter, DJ; Quenum, S | 1 |
| Procter, DJ; Szostak, M | 1 |
| Procter, DJ; Spain, M; Szostak, M | 6 |
| Parmar, D; Procter, DJ; Spain, M; Szostak, M | 1 |
| Furumaki, M; Hanamura, S; Murai, H; Sono, M; Tori, M | 1 |
| Burke, TR; Nelson, CG | 1 |
| Gilles, P; Py, S | 1 |
| Collins, KD; Fazakerley, NJ; Procter, DJ; Spain, M; Szostak, M | 1 |
| Huang, PQ; Py, S; Xu, CP | 1 |
| Honda, T | 1 |
| Matsubara, H; Parmar, D; Price, K; Procter, DJ; Spain, M | 1 |
| Fuse, S; Masui, H; Takahashi, T | 1 |
| Procter, DJ; Sautier, B | 1 |
| Ise, N; Shoji, T; Sono, M; Tori, M | 1 |
| Lindel, T; Schöttner, E; Simon, K; Wefer, J | 1 |
| Hoz, S; Rao, CN | 1 |
| Choquette, KA; Flowers, RA; Sadasivam, DV | 1 |
| Burtoloso, AC; Pinho, VD; Procter, DJ | 1 |
| Ankner, T; Hilmersson, G; Stålsmeden, AS | 1 |
| Kikuchi, N; Nakashima, K; Shiozawa, T; Takaoka, S; Takehara, T; Tori, M | 1 |
| Murata, Y; Sengoku, T; Sudo, T; Takahashi, M; Yoda, H | 1 |
| Choquette, KA; Flowers, RA; Procter, DJ; Spain, M; Szostak, M | 1 |
| Behlendorf, M; Procter, DJ; Sautier, B; Spain, M; Szostak, M | 1 |
| Daniels, DS; Smith, AD; Taylor, JE | 1 |
| Beemelmanns, C; Gross, S; Reissig, HU | 1 |
| Procter, DJ; Sautier, B; Spain, M; Szostak, M | 2 |
| Beau, JM; Doisneau, G; Le, TX; Papin, C | 1 |
| Lyons, SE; Procter, DJ; Spain, M; Szostak, M | 1 |
| Iwasaki, H; Kojima, N; Ozeki, M; Suzuki, K; Yamane, M; Yamashita, M; Yoshida, S | 1 |
| Chen, R; Li, CC; Liu, G; Mei, G; Yang, Z; Yuan, H | 1 |
| Lyons, SE; Procter, DJ; Webb, MR; Yalavac, I | 1 |
| Jiménez, C; Montaos, MA; Rodríguez, J; Segade, Y | 1 |
| Hu, Y; Lee, CC; Ribbe, MW | 1 |
| Guo, S; Liu, J; Ma, D | 1 |
| Aoyama, H; Shigeoka, D; Suizu, H; Yoshimitsu, T | 1 |
| Just-Baringo, X; Procter, DJ | 1 |
| Cabianca, E; Chéry, F; De Lucchi, O; Lindhorst, TK; Rollin, P; Tatibouët, A | 1 |
| Lalancette, R; Shi, S; Szostak, M; Szostak, R | 1 |
| Kolmar, SS; Mayer, JM | 1 |
| Matsuda, F; Miyano, N; Suzuki, J; Umezawa, T; Yashiro, S | 1 |
| Shi, S; Szostak, M | 1 |
| Aretz, CD; Cowen, BJ; Eaton, GR; Eaton, SS; McPeak, JE | 1 |
| Garduño-Castro, MH; Just-Baringo, X; Lenz, P; Plesniak, MP; Procter, DJ | 1 |
| Nishibuchi, Y; Sono, M; Tori, M; Yamaguchi, N | 1 |
| Li, T; Liu, X; Luo, S; Xu, Z; Zhang, Z | 1 |
| Fukuda, H; Ishihara, J; Komine, K; Ninomiya, R | 1 |
| Kikuta, K; Kume, S; Morimoto, Y; Nakatsukasa, H; Nishikawa, K; Sugahara, S; Tsuruta, T | 1 |
| Gour, J; Kar, S; Mahammad Ghouse, S; Manohar Chelli, S; Nanduri, S; Pawar, G; Reddy Dannarm, S; Sonti, R | 1 |
| Amalina, I; Crisenza, GEM; Kaltsoyannis, N; Morrill, C; Péter, Á; Procter, DJ; Pye, E | 1 |
| Bernz, A; Bilitewski, U; Claasen, B; Holzwarth, M; Laschat, S; Ludwig, J; Majoul, A; Pawletta, B; Reuter, J; Weiss, IM; Zens, A | 1 |
| Guo, JM; Li, X; Liu, CH; Si, CM; Sun, JT; Wei, BG | 1 |
| Achazi, AJ; Kelterer, AM; Miro, P; Paulus, B; Steiner, L; Vlaisavljevich, B | 1 |
Reviews
16 review(s) available for samarium and iodine
| Article | Year |
|---|---|
[Syntheses of biologically active natural products using metal-mediated reactions as key reactions].
Topics: Bromine Compounds; Catalysis; Chlorides; Chromium Compounds; Cyclization; Indicators and Reagents; Indoles; Iodides; Oxidation-Reduction; Palladium; Pyrroles; Pyrrolidines; Pyrrolizidine Alkaloids; Samarium | 2000 |
[6-endo-trig mode cyclization to a hydrindanone using samarium (II) iodide].
Topics: Cyclization; Cycloparaffins; Indenes; Iodides; Molecular Conformation; Samarium; Stereoisomerism | 2003 |
Samarium(II)-iodide-mediated cyclizations in natural product synthesis.
Topics: Biological Factors; Cyclization; Iodides; Samarium | 2004 |
Beta-elimination reactions by using samarium diiodide.
Topics: Alkenes; Iodides; Molecular Structure; Organic Chemicals; Samarium | 2004 |
Recent advances in the synthesis of C-oligosaccharides.
Topics: Anions; Cations; Cyclization; Free Radicals; Iodides; Oligosaccharides; Oxidation-Reduction; Samarium | 2005 |
[Synthetic study of nucleoside antibiotics].
Topics: Anti-Bacterial Agents; Azepines; Chemistry, Organic; Iodides; Nucleosides; Organic Chemistry Phenomena; Purine Nucleosides; Samarium; Uracil; Uridine | 2006 |
[Medicinal chemistry targeting nucleosides and nucleic acids based on fine synthetic chemistry].
Topics: Animals; Chemistry, Organic; Chemistry, Pharmaceutical; Drug Design; HMGB1 Protein; Humans; Iodides; NF-kappa B; Nucleic Acids; Nucleosides; Oligodeoxyribonucleotides; Samarium | 2008 |
Samarium diiodide mediated reactions in total synthesis.
Topics: Catalysis; Cyclization; Indicators and Reagents; Iodides; Molecular Structure; Paclitaxel; Samarium; Stereoisomerism; Structure-Activity Relationship | 2009 |
SmI(2)-induced reductive cyclizations for the synthesis of cyclic ethers and applications in natural product synthesis.
Topics: Biological Products; Cyclization; Ethers, Cyclic; Iodides; Samarium; Stereoisomerism | 2010 |
SmI2-induced cyclizations and their applications in natural product synthesis.
Topics: Biological Products; Ciguatoxins; Cyclization; Ethers; Heterocyclic Compounds, 4 or More Rings; Iodides; Lactones; Marine Toxins; Oxocins; Polymers; Pyrans; Samarium | 2010 |
Stereospecific and highly stereoselective cyclopropanation reactions promoted by samarium.
Topics: Cyclopropanes; Iodides; Molecular Structure; Samarium; Stereoisomerism | 2010 |
Samarium diiodide induced ketyl-(het)arene cyclisations towards novel N-heterocycles.
Topics: Aniline Compounds; Azasteroids; Biological Products; Cyclization; Heterocyclic Compounds; Indoles; Iodides; Ketones; Pyrroles; Samarium; Strychnine | 2011 |
Selective reductive transformations using samarium diiodide-water.
Topics: Amines; Biological Products; Iodides; Lactones; Nitrogen Oxides; Oxazolidinones; Oxidation-Reduction; Samarium; Water | 2012 |
Investigation of innovative synthesis of biologically active compounds on the basis of newly developed reactions.
Topics: Biological Products; Chemistry, Pharmaceutical; Drug Discovery; Iodides; Molecular Structure; Samarium | 2012 |
Recent advances in the chemistry of SmI(2)-H(2)O.
Topics: Alcohols; Cyclization; Esters; Iodides; Molecular Structure; Oxidation-Reduction; Samarium; Water | 2012 |
Synthesis of Nitrogen Heterocycles Using Samarium(II) Iodide.
Topics: Biological Products; Chemistry Techniques, Synthetic; Cyclization; Iodides; Nitrogen; Pharmaceutical Preparations; Samarium | 2017 |
Other Studies
138 other study(ies) available for samarium and iodine
| Article | Year |
|---|---|
Reduction of patient exposure by use of heavy elements as radiation filters in diagnostic radiology.
Topics: Aluminum; Filtration; Gadolinium; Holmium; Humans; Iodine; Radiation Dosage; Radiation Protection; Samarium; Skin; Spine; Tungsten; Urography; Ytterbium | 1978 |
Attempted reduction of 1,2,3-thiadiazole-4-carboxylates with samarium/iodine in methanol. Unexpected ring enlargement to 1,2,5-trithiepan-4,6-dicarboxylates.
Topics: Heterocyclic Compounds, 1-Ring; Iodine; Methanol; Molecular Structure; Oxidation-Reduction; Samarium; Thiadiazoles | 2004 |
Samarium Barbier reactions of alpha-iodomethyloxazoles and thiazoles with aliphatic aldehydes.
Topics: Aldehydes; Heterocyclic Compounds, 4 or More Rings; Iodine; Methylation; Molecular Structure; Oxazoles; Samarium; Thiazoles | 2005 |
The first synthesis of herbicidin B, a tricyclic-sugar adenine nucleoside antibiotic, using samarium diiodide-promoted aldol-type C-glycosidation reaction as a key-step.
Topics: Anti-Bacterial Agents; Drug Design; Indicators and Reagents; Iodides; Molecular Conformation; Molecular Structure; Purine Nucleosides; Samarium | 1999 |
An unusual samarium diiodide mediated reductive ring contraction of a tricyclic oxazine to a highly-functionalized cyclopentane and cyclobutane.
Topics: Cyclobutanes; Cyclopentanes; Indicators and Reagents; Iodides; Models, Molecular; Molecular Conformation; Oxazines; Pseudomonas putida; Samarium | 2000 |
The first directed reduction of beta-alkoxy ketones to anti-1,3-diol monoethers: identification of spectator and director alkoxy groups.
Topics: Deuterium; Ethers; Iodides; Ketones; Oxidation-Reduction; Samarium; Stereoisomerism | 2000 |
Reductive dimerization of alkylidenemalonates using samarium(II) diiodide and 1H-NMR behavior of the dimers, 2,3-diaryl-1,1,4,4-butanetetracarboxylates.
Topics: Butanes; Carboxylic Acids; Crystallography, X-Ray; Dimerization; Indicators and Reagents; Iodides; Magnetic Resonance Spectroscopy; Malonates; Molecular Structure; Samarium | 2000 |
Reduction of acetals with samarium diiodide in acetonitrile in the presence of Lewis acids.
Topics: Acetals; Acetonitriles; Acids; Iodides; Oxidation-Reduction; Samarium; Spectrum Analysis | 2001 |
Sequenced reactions with samarium(II) iodide. Sequential intramolecular Barbier cyclization/Grob fragmentation for the synthesis of medium-sized carbocycles.
Topics: Alkanes; Alkylation; Cyclization; Iodides; Ketones; Oxidation-Reduction; Samarium | 2001 |
Sequential elimination-reduction reactions promoted by samarium diiodide: synthesis of 2,3-dideuterioesters or -amides.
Topics: Amides; Deuterium; Esters; Iodides; Isotope Labeling; Samarium | 2001 |
SmI(2)-mediated cyclizations of derivatized beta-lactams for the highly diastereoselective construction of functionalized prolines.
Topics: Azetidines; beta-Lactams; Catalysis; Chemistry, Organic; Chromatography, Thin Layer; Cyclization; Iodides; Magnetic Resonance Spectroscopy; Molecular Structure; Proline; Samarium; Stereoisomerism | 2002 |
Sequenced reactions with samarium(II) iodide. Sequential intramolecular Reformatsky/nucleophilic acyl substitution reactions for the synthesis of medium-sized carbocycles.
Topics: Alkanes; Alkylation; Catalysis; Cyclization; Iodides; Ketones; Molecular Structure; Samarium | 2002 |
Samarium(II) iodide-mediated intramolecular conjugate additions of alpha,beta-unsaturated lactones.
Topics: Cyclization; Hydrocarbons, Halogenated; Iodides; Lactones; Samarium | 2002 |
Mechanistic study of beta-substituent effects on the mechanism of ketone reduction by SmI(2).
Topics: Acetophenones; Butanones; Iodides; Ketones; Kinetics; Oxidation-Reduction; Samarium; Thermodynamics | 2002 |
Directed reduction of beta-amino ketones to syn or anti 1,3-amino alcohol derivatives.
Topics: Amines; Amino Alcohols; Anti-Bacterial Agents; Biological Factors; Hydrogenation; Iodides; Ketones; Molecular Structure; Samarium; Stereoisomerism | 2002 |
Samarium diiodide-mediated reductive coupling of epoxides and carbonyl compounds: a stereocontrolled synthesis of C-glycosides from 1,2-anhydro sugars.
Topics: Epoxy Compounds; Glycosides; Indicators and Reagents; Iodides; Oxidation-Reduction; Samarium; Stereoisomerism | 2002 |
A highly stereoselective samarium diiodide-promoted aldol reaction with 1'-phenylseleno-2'-keto nucleosides. Synthesis of 1'alpha-branched uridine derivatives.
Topics: Aldehydes; Iodides; Molecular Structure; Nucleosides; Oxidation-Reduction; Samarium; Stereoisomerism; Structure-Activity Relationship; Temperature; Uridine | 2002 |
SmI(2)-promoted radical addition of nitrones to alpha,beta-unsaturated amides and esters: synthesis of gamma-amino acids via a nitrogen equivalent to the ketyl radical.
Topics: Amides; Amino Acids; Esters; Free Radicals; Iodides; Nitrogen Oxides; Samarium | 2003 |
Samarium(II) iodide mediated radical/polar crossover reactions of cyclobutenes. An efficient approach to the BCD ring system of the penitrems.
Topics: Alkaloids; Cyclization; Cyclobutanes; Free Radicals; Hydrocarbons, Cyclic; Iodides; Mycotoxins; Samarium | 2003 |
Instantaneous SmI2/H2O/amine-mediated reductions in THF.
Topics: Amines; Carcinogens; Hydrogenation; Iodides; Oxidation-Reduction; Samarium; Water | 2003 |
Synthesis of the C-linked disaccharide alpha-D-Man-(1-->4)-D-Man employing a SmI(2)-mediated C-glycosylation step: en route to cyclic C-oligosaccharides.
Topics: Catalysis; Combinatorial Chemistry Techniques; Disaccharides; Glycosylation; Indicators and Reagents; Iodides; Mannosides; Molecular Structure; Nuclear Magnetic Resonance, Biomolecular; Oligosaccharides; Ozone; Samarium; Stereoisomerism | 2003 |
SmI2 reduced thioesters as synthons of unstable acyl radicals: direct synthesis of potential protease inhibitors via intermolecular radical addition.
Topics: Acrylamides; Amides; Benzyl Compounds; Esters; Free Radicals; Iodides; Ketones; Oxidation-Reduction; Protease Inhibitors; Pyridines; Samarium; Sulfhydryl Compounds | 2003 |
The second total synthesis of diazonamide A.
Topics: Biological Factors; Cyclization; Heterocyclic Compounds, 4 or More Rings; Indoles; Iodides; Molecular Structure; Oxazoles; Samarium; Stereoisomerism | 2003 |
Mass spectrometric studies of cyclopentanol derivatives in the reductive coupling of alpha,beta-unsaturated ketones assisted by samarium diiodide.
Topics: Cyclopentanes; Iodides; Ketones; Oxidation-Reduction; Reproducibility of Results; Samarium; Spectrometry, Mass, Fast Atom Bombardment | 2003 |
A highly selective route to beta-C-glycosides via nonselective samarium iodide induced coupling reactions.
Topics: Carbohydrate Conformation; Glycosides; Iodides; Isomerism; Molecular Structure; Oxidation-Reduction; Samarium | 2003 |
Application of samarium diiodide (SmI2)-induced reduction of gamma-acetoxy-alpha,beta-enoates with alpha-specific kinetic electrophilic trapping for the synthesis of amino acid derivatives.
Topics: Acetates; Amino Acids; Iodides; Kinetics; Models, Chemical; Organometallic Compounds; Oxidation-Reduction; Samarium; Stereoisomerism | 2003 |
SmI2/water/amine mediates cleavage of allyl ether protected alcohols: application in carbohydrate synthesis and mechanistic considerations.
Topics: Alcohols; Allyl Compounds; Amines; Carbohydrates; Catalysis; Ethers; Ethylamines; Iodides; Molecular Structure; Phenyl Ethers; Propylamines; Samarium; Water | 2003 |
The first transformation of aliphatic alpha,beta-epoxyamides into alpha-hydroxyamides.
Topics: Amides; Epoxy Compounds; Iodides; Molecular Structure; Samarium; Stereoisomerism | 2003 |
Total synthesis of (+)-isoschizandrin utilizing a samarium(II) iodide-promoted 8-endo ketyl-olefin cyclization.
Topics: Alkenes; Aza Compounds; Boron Compounds; Cyclization; Cyclooctanes; Iodides; Ketones; Lactones; Lignans; Models, Chemical; Molecular Structure; Polycyclic Compounds; Samarium; Schisandra; Stereoisomerism | 2003 |
Trifluoroacetyl-activated nitrogen-nitrogen bond cleavage of hydrazines by samarium(II) iodide.
Topics: Hydrazines; Hydrocarbons, Fluorinated; Iodides; Molecular Structure; Nitrogen; Samarium | 2004 |
SmI2-mediated reduction of gamma,gamma-difluoro-alpha,beta-enoates with application to the synthesis of functionalized (Z)-fluoroalkene-type dipeptide isosteres.
Topics: Alkenes; Dipeptides; Hydrocarbons, Fluorinated; Imines; Iodides; Magnetic Resonance Spectroscopy; Molecular Structure; Samarium; Stereoisomerism | 2004 |
Synthesis of tunicaminyluracil derivatives.
Topics: Anti-Bacterial Agents; Cold Temperature; Iodides; Samarium; Tunicamycin; Uracil | 2004 |
Synthesis of (E)-alpha-hydroxy-beta,gamma-unsaturated amides with high selectivity from alpha,beta-epoxyamides by using catalytic samarium diiodide or triiodide.
Topics: Amides; Catalysis; Epoxy Compounds; Iodides; Magnetic Resonance Spectroscopy; Mass Spectrometry; Molecular Structure; Samarium; Spectrophotometry, Infrared; Stereoisomerism | 2004 |
Diastereoselective conjugate reduction with samarium diiodide: asymmetric synthesis of methyl (2S,3R)-N-acetyl-2-amino-2,3-dideuterio-3-phenylpropionate.
Topics: Iodides; Molecular Structure; Oxidation-Reduction; Phenylpropionates; Samarium; Stereoisomerism | 2004 |
Intramolecular, reductive cyclization of beta-ketoisothiocyanates promoted by using samarium diiodide.
Topics: Cyclization; Iodides; Isothiocyanates; Ketones; Lactams; Magnetic Resonance Spectroscopy; Molecular Structure; Samarium; Spectrophotometry, Infrared | 2005 |
Syntheses of (+)-cytisine, (-)-kuraramine, (-)-isokuraramine, and (-)-jussiaeiine A.
Topics: Alkaloids; Azocines; Cyclization; Deamination; Drug Design; Iodides; Molecular Structure; Piperidines; Pyridines; Quinolizines; Samarium; Stereoisomerism | 2005 |
Samarium diiodide promoted generation and asymmetric hydroxyalkylation of N,O-diprotected (3S)-3-pyrrolidinol 2-carbanions.
Topics: Anions; Carbamates; Hydroxylation; Iodides; Magnetic Resonance Spectroscopy; Models, Molecular; Pyrrolidines; Samarium | 2005 |
Total synthesis of (+)-hyacinthacine A2 based on SmI2-induced nitrone umpolung.
Topics: Azepines; Iodides; Molecular Conformation; Molecular Structure; Nitrogen Oxides; Pyrroles; Pyrrolizidine Alkaloids; Samarium | 2005 |
Ketyl-allene cyclizations promoted by samarium(II) iodide.
Topics: Iodides; Samarium | 2005 |
Asymmetric conjugate reductions with samarium diiodide: asymmetric synthesis of (2S,3R)- and (2S,3S)-[2-2H,3-2H]-leucine-(S)-phenylalanine dipeptides and (2S,3R)-[2-(2)H,3-2H]-phenylalanine methyl ester.
Topics: Crystallography, X-Ray; Dipeptides; Iodides; Magnetic Resonance Spectroscopy; Molecular Structure; Oxidation-Reduction; Phenylalanine; Samarium; Stereoisomerism | 2005 |
Highly functionalised cyclobutanols via samarium(II) iodide-induced pinacol cyclisations of carbohydrate-derived 1,4-diketones.
Topics: Antiviral Agents; Arabinose; Butanols; Carbohydrate Sequence; Cyclization; Cyclobutanes; Iodides; Ketones; Molecular Sequence Data; Ribose; Samarium | 2005 |
Ketone-imide versus ketone-oxime reductive cross-coupling promoted by samarium diiodide: new mechanistic insight gained from a failed aminocyclopentitol synthesis.
Topics: Cyclization; Glucosamine; Glucosidases; Imides; Iodides; Ketones; Oximes; Samarium; Stereoisomerism | 2005 |
Evaluation of a new linker system cleaved using samarium(II) iodide. Application in the solid phase synthesis of carbonyl compounds.
Topics: Iodides; Magnetic Resonance Spectroscopy; Samarium; Spectrometry, Mass, Electrospray Ionization | 2005 |
Facile deoxygenation of dicarbonyl compounds using a samarium diiodide-additive system.
Topics: Carboxylic Acids; Iodides; Ketones; Oxygen; Samarium; Spectrophotometry, Infrared | 2005 |
Synthesis of complex nucleoside antibiotics.
Topics: Adenosine; Anti-Bacterial Agents; Chemistry, Pharmaceutical; Drug Design; Heterocyclic Compounds, 3-Ring; Iodides; Ketones; Models, Chemical; Nucleosides; Purine Nucleosides; Samarium; Tunicamycin; Uracil | 2005 |
Samarium diiodide-induced intramolecular pinacol coupling of dinitrones: synthesis of cyclic cis-vicinal diamines.
Topics: Crystallography, X-Ray; Cyclization; Diamines; Glucosides; Heterocyclic Compounds; Hydrazones; Iodides; Magnetic Resonance Spectroscopy; Models, Molecular; Molecular Structure; Nitrogen Oxides; Oximes; Pyrimidinones; Samarium | 2005 |
Synthesis of 7-substituted-5-androstene derivatives promoted by SmI2.
Topics: Androstenes; Carbon Isotopes; Chromatography; Iodides; Magnetic Resonance Spectroscopy; Molecular Conformation; Samarium; Stereoisomerism | 2006 |
Extension to 2268 atoms of direct methods in the ab initio determination of the unknown structure of bacteriophage P22 lysozyme.
Topics: Bacteriophage P22; Binding Sites; Crystallization; Crystallography, X-Ray; Iodides; Models, Molecular; Molecular Structure; Muramidase; Mutagenesis, Site-Directed; Protein Conformation; Samarium | 2006 |
Estimating the limiting reducing power of SmI2/H2O/amine and YbI2/H2O/amine by efficient reduction of unsaturated hydrocarbons.
Topics: Alkenes; Amines; Electrochemistry; Hydrocarbons; Iodides; Oxidation-Reduction; Samarium; Ytterbium | 2006 |
Remarkable rate acceleration of SmI3-mediated iodination of acetates of Baylis-Hillman adducts in ionic liquid: facile synthesis of (Z)-allyl iodides.
Topics: Acetates; Iodides; Ions; Kinetics; Samarium; Solutions | 2006 |
Solid phase approaches to N-heterocycles using a sulfur linker cleaved by SmI2.
Topics: Cross-Linking Reagents; Cyclization; Heterocyclic Compounds; Indoles; Iodides; Molecular Structure; Oxindoles; Samarium; Sulfur | 2006 |
Creating carbon-carbon bonds with samarium diiodide for the synthesis of modified amino acids and peptides.
Topics: Alkylation; Amides; Amino Acids; Carbon; Esters; Fumarates; Glycine; Glycosylation; Iodides; Ketones; Nitrogen; Peptides; Samarium | 2006 |
Total synthesis of platensimycin.
Topics: Adamantane; Aminobenzoates; Anilides; Anti-Bacterial Agents; Indicators and Reagents; Iodides; Magnetic Resonance Spectroscopy; Samarium; Spectrometry, Mass, Electrospray Ionization; Spectrophotometry, Infrared; Structure-Activity Relationship | 2006 |
Samarium(II) promoted stereoselective synthesis of antiproliferative cis-beta-alkoxy-gamma-alkyl-gamma-lactones.
Topics: Antineoplastic Agents; Cell Line, Tumor; Cell Proliferation; Humans; Iodides; Lactones; Samarium; Stereoisomerism; Structure-Activity Relationship | 2007 |
SmI(2)-promoted radical addition reactions with N-(2-Indolylacyl)oxazolidinones: synthesis of bisindole compounds.
Topics: Acrylamide; Dimerization; Indoles; Iodides; Molecular Structure; Oxazolidinones; Proline; Samarium | 2007 |
A new, efficient and stereoselective synthesis of tricyclic and tetracyclic compounds by samarium diiodide induced cyclisations of naphthyl-substituted arylketones--an easy access to steroid-like skeletons.
Topics: Alkylation; Aza Compounds; Cyclization; Iodides; Ketones; Macrocyclic Compounds; Models, Molecular; Molecular Structure; Naphthalenes; Nitrogen; Pyrrolidines; Samarium; Stereoisomerism; Steroids | 2007 |
Efficient chirality transfer in the SmI2-mediated cyclization of aldehydo beta-alkoxyvinyl sulfoxides: asymmetric synthesis of 3-hydroxyoxanes.
Topics: Cyclization; Iodides; Peroxides; Samarium; Stereoisomerism; Sulfoxides | 2007 |
Direct entry to peptidyl ketones via SmI2-mediated C-C bond formation with readily accessible N-peptidyl oxazolidinones.
Topics: Acrylamides; Amines; Amino Acids; Carbon; Free Radicals; Iodides; Ketones; Molecular Structure; Oxazolidinones; Peptides; Samarium | 2008 |
Fine synthetic nucleoside chemistry based on nucleoside natural products synthesis.
Topics: Adenosine; Anti-Bacterial Agents; Bacterial Proteins; Biological Products; Chemistry, Organic; Heterocyclic Compounds, 3-Ring; Iodides; Monosaccharides; Nucleosides; Oligopeptides; Organic Chemistry Phenomena; Samarium; Structure-Activity Relationship; Transferases; Transferases (Other Substituted Phosphate Groups); Uracil | 2008 |
Pinacol macrocyclization-based route to the polyfused medium-sized CDE ring system of lancifodilactone G.
Topics: Cyclooctanes; Iodides; Macrocyclic Compounds; Samarium; Triterpenes | 2008 |
Total synthesis of (-)-kendomycin.
Topics: Cyclization; Iodides; Rifabutin; Samarium; Stereoisomerism | 2008 |
Samarium(II)-mediated spirocyclization by intramolecular aryl radical addition onto an aromatic ring.
Topics: Benzamides; Cyclization; Free Radicals; Indoles; Iodides; Molecular Structure; Samarium; Spiro Compounds; Stereoisomerism | 2008 |
General, stereoselective synthesis of (Z)-beta,gamma-unsaturated nitriles promoted by samarium diiodide.
Topics: Iodides; Molecular Structure; Nitriles; Samarium; Stereoisomerism | 2008 |
Reduction of benzophenones with SmI2. Post electron transfer processes.
Topics: Benzophenones; Electron Transport; Iodides; Kinetics; Molecular Structure; Oxidation-Reduction; Samarium; Stereoisomerism | 2009 |
Facile synthesis of a benzindenoazepine alkaloid, bulgaramine, via samarium diiodide promoted ring expansion of an alpha-aminocarbonyl compound.
Topics: Alkaloids; Azepines; Cyclization; Fumaria; Heterocyclic Compounds, 4 or More Rings; Iodides; Molecular Structure; Samarium | 2009 |
Selective reductions of cyclic 1,3-diesters using SmI(2) and H(2)O.
Topics: Esters; Free Radicals; Hydroxy Acids; Iodides; Reducing Agents; Samarium; Water | 2009 |
A new approach to 3-hydroxyprolinol derivatives by samarium diiodide-mediated reductive coupling of chiral nitrone with carbonyl compounds.
Topics: Humans; Iodides; Ketones; Nitrogen Oxides; Oxidation-Reduction; Pyrrolidines; Samarium; Stereoisomerism | 2009 |
Medium-sized carbocycles by samarium diiodide-induced carbonyl-alkene cyclizations.
Topics: Alkenes; Catalysis; Cyclization; Iodides; Molecular Structure; Samarium | 2009 |
SmI(2)-mediated carbon-carbon bond fragmentation in alpha-aminomethyl malonates.
Topics: Amino Sugars; Carbon; Cyclization; Iodides; Malonates; Molecular Structure; Samarium; Structure-Activity Relationship; Temperature | 2009 |
Samarium diiodide-induced reductive cross-coupling of nitrones with aldehydes and ketones.
Topics: Alcohols; Aldehydes; Carbon; Electron Spin Resonance Spectroscopy; Free Radicals; Hempa; Iodides; Ketones; Models, Chemical; Nitrogen; Nitrogen Oxides; Organic Chemicals; Oxygen; Samarium; Time Factors | 2002 |
Studies on the mechanism, selectivity, and synthetic utility of lactone reduction using SmI(2) and H(2)O.
Topics: Cyclization; Iodides; Kinetics; Lactones; Models, Molecular; Molecular Structure; Oxidation-Reduction; Samarium; Stereoisomerism; Water | 2009 |
Highly diastereoselective samarium diiodide induced cyclizations of new 3-substituted indole derivatives.
Topics: Acetonitriles; Alkaloids; Cyclization; Indoles; Iodides; Ketones; Samarium; Stereoisomerism; Substrate Specificity | 2009 |
One-pot cross-coupling of N-acyl N,O-acetals with alpha,beta-unsaturated compounds.
Topics: Acetals; Boranes; Iodides; Pyrrolizidine Alkaloids; Samarium; Stereoisomerism | 2009 |
Synthesis and application of a new fluorous-tagged ammonia equivalent.
Topics: Amides; Ammonia; Benzamides; Benzyl Compounds; Carbamates; Combinatorial Chemistry Techniques; Dyspepsia; Hydrocarbons, Fluorinated; Indicators and Reagents; Iodides; Molecular Structure; Molybdenum; Nitrogen; Oxygen; Samarium; Sulfonamides; Urea | 2010 |
Total synthesis and structural revision of vannusals A and B: synthesis of the originally assigned structure of vannusal B.
Topics: Aldehydes; Cyclization; Iodides; Samarium; Spiro Compounds; Stereoisomerism | 2010 |
Selective reductions of cyclic 1,3-diesters by using SmI(2) and H(2)O.
Topics: Dioxanes; Esters; Free Radicals; Hydroxy Acids; Iodides; Reducing Agents; Samarium; Water | 2010 |
Selective α-defluorination of polyfluorinated esters and amides using SmI2/Et3N/H2O.
Topics: Amides; Amines; Esters; Ethylamines; Halogenation; Iodides; Samarium; Water | 2010 |
A short formal total synthesis of strychnine with a samarium diiodide induced cascade reaction as the key step.
Topics: Biological Products; Iodides; Samarium; Strychnine; Strychnos | 2010 |
SmI2-mediated radical cyclizations directed by a C-Si bond.
Topics: Carbon; Cyclization; Iodides; Models, Molecular; Molecular Structure; Oxidation-Reduction; Samarium; Silicon; Stereoisomerism | 2010 |
Reductive cyclization cascades of lactones using SmI2-H2O.
Topics: Cyclization; Iodides; Lactones; Molecular Structure; Oxidation-Reduction; Samarium; Stereoisomerism; Water | 2011 |
A concise approach for the total synthesis of pseudolaric acid A.
Topics: Biological Products; Cyclization; Diterpenes; Iodides; Molecular Structure; Pinaceae; Samarium; Stereoisomerism | 2011 |
SmI2-mediated radical cross-couplings of α-hydroxylated aza-hemiacetals and N,S-acetals with α,β-unsaturated compounds: asymmetric synthesis of (+)-hyacinthacine A2, (-)-uniflorine A, and (+)-7-epi-casuarine.
Topics: Acetals; Alkaloids; Aza Compounds; Free Radicals; Hydroxylation; Indolizines; Iodides; Molecular Structure; Pyrroles; Pyrrolizidine Alkaloids; Samarium; Stereoisomerism | 2011 |
Exploiting Sm(II) and Sm(III) in SmI2-initiated reaction cascades: application in a tag removal-cyclisation approach to spirooxindole scaffolds.
Topics: Cyclization; Iodides; Molecular Structure; Samarium; Spiro Compounds; Stereoisomerism | 2011 |
Concise syntheses of strychnine and englerin A: the power of reductive cyclizations triggered by samarium iodide.
Topics: Chemistry Techniques, Synthetic; Cyclization; Iodides; Molecular Structure; Oxidation-Reduction; Samarium; Sesquiterpenes, Guaiane; Stereoisomerism; Strychnine | 2011 |
Electron transfer reduction of unactivated esters using SmI2-H2O.
Topics: Electron Transport; Esters; Iodides; Kinetics; Metals, Alkali; Samarium; Water | 2011 |
First direct evidence of radical intermediates in samarium diiodide induced cyclization by ESR spectra.
Topics: Cyclization; Electron Spin Resonance Spectroscopy; Free Radicals; Iodides; Molecular Structure; Oxidation-Reduction; Samarium | 2011 |
Samarium iodide-mediated Reformatsky reactions for the stereoselective preparation of β-hydroxy-γ-amino acids: synthesis of isostatine and dolaisoleucine.
Topics: Amino Acids; Iodides; Molecular Structure; Samarium; Stereoisomerism | 2012 |
Electron transfer reduction of carboxylic acids using SmI2-H2O-Et3N.
Topics: Carboxylic Acids; Electrons; Ethylamines; Iodides; Molecular Structure; Oxidation-Reduction; Samarium; Water | 2012 |
SmI2-mediated cross-coupling of nitrones with β-silyl acrylates: synthesis of (+)-australine.
Topics: Acrylates; Iodides; Molecular Structure; Nitrogen Oxides; Oxidation-Reduction; Pyrrolizidine Alkaloids; Samarium; Stereoisomerism; Zinc | 2012 |
A general electron transfer reduction of lactones using SmI2-H2O.
Topics: Electron Transport; Iodides; Lactones; Samarium; Substrate Specificity; Water | 2012 |
Preparation of samarium(II) iodide: quantitative evaluation of the effect of water, oxygen, and peroxide content, preparative methods, and the activation of samarium metal.
Topics: Indicators and Reagents; Iodides; Metals; Molecular Structure; Oxygen; Peroxides; Samarium; Stereoisomerism; Water | 2012 |
SmI2-mediated coupling of nitrones and tert-butanesulfinyl imines with allenoates: synthesis of β-methylenyl-γ-lactams and tetramic acids.
Topics: beta-Lactams; Esters; Imines; Iodides; Molecular Structure; Nitrogen Oxides; Pyrrolidinones; Samarium; Stereoisomerism; Zinc | 2012 |
Selective synthesis of 3-hydroxy acids from Meldrum's acids using SmI2-H2O.
Topics: Chemistry, Organic; Dioxanes; Hydroxy Acids; Iodides; Samarium; Water | 2012 |
Lactone radical cyclizations and cyclization cascades mediated by SmI2-H2O.
Topics: Alkenes; Alkynes; Cyclization; Iodides; Lactones; Oxidation-Reduction; Samarium; Stereoisomerism; Water | 2012 |
One-pot, three-component coupling approach to the synthesis of α-iminocarboxamides.
Topics: Amides; Combinatorial Chemistry Techniques; Imines; Iodides; Isocyanates; Molecular Structure; Samarium; Stereoisomerism | 2012 |
Cyclizations producing hydrindanones with two methyl groups at the juncture positions mediated by samarium diiodide and electrolysis.
Topics: Aldehydes; Cyclization; Electrolysis; Indans; Iodides; Ketones; Molecular Structure; Samarium; Stereoisomerism | 2012 |
Enantioselective total synthesis of the diterpene (+)-cubitene.
Topics: Animals; Cyclization; Diterpenes; Iodides; Isoptera; Magnetic Resonance Spectroscopy; Molecular Conformation; Phosphates; Samarium; Stereoisomerism; Terpenes | 2012 |
Synergism and inhibition in the combination of visible light and HMPA in SmI2 reductions.
Topics: Acetylene; Benzoates; Hempa; Iodides; Light; Molecular Structure; Naphthalenes; Nitriles; Oxidation-Reduction; Samarium | 2012 |
Preparation and use of samarium diiodide (SmI(2)) in organic synthesis: the mechanistic role of HMPA and Ni(II) salts in the samarium Barbier reaction.
Topics: Acetates; Cations, Divalent; Chemistry Techniques, Synthetic; Hempa; Iodides; Nickel; Organometallic Compounds; Samarium | 2013 |
SmI2-mediated couplings of α-amino acid derivatives. Formal synthesis of (-)-pumiliotoxin 251D and (±)-epiquinamide.
Topics: Acrylates; Amino Acids; Indolizines; Iodides; Molecular Structure; Quinolizines; Samarium; Stereoisomerism | 2013 |
Selective cleavage of 3,5-bis-(trifluoromethyl)benzylcarbamate by SmI2-Et3N-H2O.
Topics: Amines; Carbamates; Ethylamines; Iodides; Molecular Structure; Samarium; Water | 2013 |
Synthesis of a key intermediate, 10-acetyl-7-(t-butyldiphenylsilyloxymethyl)-4-methylbicyclo[5.3.0]dec-4-en-1-ol, in the synthesis of pseudolaric acid A.
Topics: Bridged Bicyclo Compounds; Cyclization; Diterpenes; Iodides; Samarium; Siloxanes; Stereoisomerism | 2013 |
Synthetic approach toward alpha-aminomethyl-gamma-butyrolactones from beta-lactam synthons elaborated by SmI2-mediated reductive coupling reactions.
Topics: 4-Butyrolactone; beta-Lactams; Iodides; Lactones; Magnetic Resonance Spectroscopy; Oxidation-Reduction; Samarium | 2013 |
Substrate-directable electron transfer reactions. Dramatic rate enhancement in the chemoselective reduction of cyclic esters using SmI2-H2O: mechanism, scope, and synthetic utility.
Topics: Alcohols; Electrons; Esters; Iodides; Molecular Structure; Oxidation-Reduction; Samarium; Water | 2013 |
Selective reduction of barbituric acids using SmI2/H2O: synthesis, reactivity, and structural analysis of tetrahedral adducts.
Topics: Barbiturates; Iodides; Oxidation-Reduction; Samarium; Water | 2013 |
Asymmetric NHC-catalyzed redox α-amination of α-aroyloxyaldehydes.
Topics: Aldehydes; Amination; Catalysis; Combinatorial Chemistry Techniques; Heterocyclic Compounds; Hydrazines; Iodides; Methane; Molecular Structure; Oxidation-Reduction; Samarium; Stereoisomerism | 2013 |
Towards the core structure of Strychnos alkaloids using samarium diiodide-induced reactions of indole derivatives.
Topics: Alkaloids; Cyclization; Indoles; Iodides; Molecular Structure; Samarium; Strychnos | 2013 |
Electron transfer reduction of nitriles using SmI2-Et3N-H2O: synthetic utility and mechanism.
Topics: Amines; Combinatorial Chemistry Techniques; Electron Transport; Iodides; Lewis Bases; Metals, Alkali; Molecular Structure; Nitriles; Samarium; Water | 2014 |
Determination of the effective redox potentials of SmI₂, SmBr₂, SmCl₂, and their complexes with water by reduction of aromatic hydrocarbons. Reduction of anthracene and stilbene by samarium(II) iodide-water complex.
Topics: Anthracenes; Electron Transport; Hydrocarbons, Aromatic; Iodides; Molecular Structure; Oxidation-Reduction; Samarium; Stilbenes; Water | 2014 |
Direct umpolung of glycals and related 2,3-unsaturated N-acetylneuraminic acid derivatives using samarium diiodide.
Topics: Iodides; Molecular Structure; Samarium; Sialic Acids | 2014 |
Mechanistic investigation of the selective reduction of Meldrum's acids to β-hydroxy acids using SmI2 and H2O.
Topics: Deuterium; Dioxanes; Electron Transport; Hydroxy Acids; Iodides; Kinetics; Oxidation-Reduction; Samarium; Water | 2014 |
Indole synthesis from N-allenyl-2-iodoanilines under mild conditions mediated by samarium(II) diiodide.
Topics: Aniline Compounds; Chemistry, Organic; Cyclization; Electrons; Hempa; Indoles; Iodides; Models, Chemical; Molecular Structure; Samarium; Temperature | 2014 |
Total synthesis of aplykurodinone-1.
Topics: Animals; Aplysia; Cyclization; Indans; Iodides; Lactones; Molecular Structure; Samarium; Stereoisomerism | 2014 |
SmI2-H2O-mediated 5-exo/6-exo lactone radical cyclisation cascades.
Topics: Alkadienes; Bridged Bicyclo Compounds; Crystallography, X-Ray; Cyclization; Indicators and Reagents; Iodides; Lactones; Models, Molecular; Oxidation-Reduction; Samarium; Stereoisomerism; Water | 2014 |
Selective synthesis of α,α-dideuterio alcohols by the reduction of carboxylic acids using SmI2 and D2O as deuterium source under SET conditions.
Topics: Alcohols; Carboxylic Acids; Combinatorial Chemistry Techniques; Deuterium; Iodides; Metals, Alkali; Molecular Structure; Samarium; Stereoisomerism | 2014 |
Switching between reaction pathways by an alcohol cosolvent effect: SmI2-ethylene glycol vs SmI2-H2O mediated synthesis of uracils.
Topics: Alcohols; Barbiturates; Ethylene Glycol; Iodides; Ions; Molecular Structure; Oxidation-Reduction; Samarium; Solvents; Uracil | 2014 |
A short stereoselective synthesis of prepiscibactin using a SmI2-mediated Reformatsky reaction and Zn2+-induced asymmetric thiazolidine formation.
Topics: Animals; Cysteine; Fish Diseases; Fishes; Iodides; Molecular Structure; Nitriles; Pasteurella Infections; Pfiesteria piscicida; Photobacterium; Samarium; Stereoisomerism; Thiazoles; Thiazolidines; Zinc | 2014 |
Catalytic reduction of CN-, CO, and CO2 by nitrogenase cofactors in lanthanide-driven reactions.
Topics: Biocatalysis; Carbon Dioxide; Carbon Monoxide; Cyanides; Gas Chromatography-Mass Spectrometry; Hydrocarbons; Iodides; Nitrogenase; Oxidation-Reduction; Samarium | 2015 |
Total synthesis of leucosceptroids A and B.
Topics: Aldehydes; Alkenes; Antifungal Agents; Catalysis; Colletotrichum; Crystallography, X-Ray; Cyclization; Free Radicals; Iodides; Molecular Conformation; Rhizoctonia; Samarium; Sesterterpenes | 2015 |
Total synthesis of clavilactone B: a radical cyclization-fragmentation strategy.
Topics: Crystallography, X-Ray; Cyclization; ErbB Receptors; Iodides; Lactones; Molecular Conformation; Molecular Structure; Samarium | 2015 |
Sm(II)-Mediated Electron Transfer to Carboxylic Acid Derivatives: Development of Complexity-Generating Cascades.
Topics: Alcohols; Amides; Carboxylic Acids; Electron Transport; Iodides; Molecular Structure; Samarium | 2015 |
Evolution of a short route to strychnine by using the samarium-diiodide-induced cascade cyclization as a key step.
Topics: Alkaloids; Cyclization; Iodides; Ketones; Molecular Structure; Samarium; Strychnine; Strychnos | 2015 |
Strychnine as Target, Samarium Diiodide as Tool: A Personal Story.
Topics: Iodides; Molecular Structure; Samarium; Strychnine | 2015 |
Reductive opening of carbohydrate phenylsulfonylethylidene (PSE) acetals.
Topics: Acetals; Benzylidene Compounds; Dioxanes; Dioxolanes; Iodides; Molecular Structure; Oxidation-Reduction; Samarium; Stereoisomerism | 2015 |
Highly Chemoselective Synthesis of Indolizidine Lactams by SmI2 -Induced Umpolung of the Amide Bond via Aminoketyl Radicals: Efficient Entry to Alkaloid Scaffolds.
Topics: Alkaloids; Alkenes; Amides; Cyclization; Electron Transport; Esters; Indolizidines; Iodides; Lactams; Molecular Structure; Nitrogen; Samarium; Water | 2016 |
SmI
Topics: Amines; Electrons; Iodides; Oxidation-Reduction; Protons; Samarium; Thermodynamics; Water | 2017 |
Total synthesis of (-)-kainic acid and (+)-allo-kainic acid through SmI
Topics: Allyl Compounds; Cyclization; Esters; Iodides; Kainic Acid; Oxidation-Reduction; Samarium | 2017 |
Mechanism of SmI
Topics: Electron Spin Resonance Spectroscopy; Iodides; Nitroso Compounds; Oxidation-Reduction; Samarium; Spin Trapping; Sulfonic Acids | 2018 |
Samarium(II) folding cascades involving hydrogen atom transfer for the synthesis of complex polycycles.
Topics: Carbohydrate Conformation; Chemistry Techniques, Synthetic; Electron Transport; Humans; Hydrogen; Iodides; Models, Chemical; Polycyclic Compounds; Samarium | 2018 |
Cyclization into Hydrindanes Using Samarium Diiodide: Stereochemical Features Depending on the Protecting Group.
Topics: Botrytis; Catalysis; Indans; Iodides; Molecular Structure; Samarium | 2016 |
Stereoselective Synthesis of β-
Topics: Glycosides; Iodides; Molecular Structure; Samarium; Stereoisomerism; Sugar Acids | 2021 |
A Stereoselective Synthesis of Fused Carbocycles with a cis-1,2-Diol Moiety by Desymmetrization: SmI
Topics: Alcohols; Glycols; Iodides; Ketones; Molecular Structure; Samarium; Stereoisomerism | 2022 |
Asymmetric Total Synthesis of Toxicodenane A by Samarium-Iodide-Induced Barbier-Type Cyclization and Its Cell-Protective Effect against Lipotoxicity.
Topics: Iodides; Samarium | 2022 |
SmI
Topics: Alcohols; Alkylation; Iodides; Ketones; Microwaves; Samarium | 2022 |
Diastereoselective Radical 1,4-Ester Migration: Radical Cyclizations of Acyclic Esters with SmI
Topics: Cyclization; Esters; Iodides; Lactones; Samarium | 2022 |
Modulating chitin synthesis in marine algae with iminosugars obtained by SmI
Topics: Carbohydrates; Chitin; Ferric Compounds; Iodides; Samarium | 2022 |
SmI
Topics: Iodides; Piperidines; Pyrrolidines; Samarium; Sulfones | 2022 |
Samarium Diiodide Acting on Acetone-Modeling Single Electron Transfer Energetics in Solution.
Topics: Acetone; Cyclization; Electron Transport; Electrons; Hempa; Iodides; Samarium | 2022 |