salvileucalin-b and cyclopropane

salvileucalin-b has been researched along with cyclopropane* in 2 studies

Other Studies

2 other study(ies) available for salvileucalin-b and cyclopropane

Article	Year
Reversible cyclopropane ring-cleavage reactions within etheno-bridged [4.3.1]propelladiene frameworks leading to aza- and oxa-[5.6.5.6]fenestratetraenes. Chemistry (Weinheim an der Bergstrasse, Germany), 2012, Oct-22, Volume: 18, Issue:43 Opening and closing a chemical window: oxidation of the etheno-bridged [4.3.1]propelladienol 1 with pyridinium chlorochromate (PCC) affords oxa[5.6.5.6]fenestratetraene 2. The reduction of 2 with diisobutylaluminum hydride (DIBAl-H) leads to the regeneration of its precursor (1). These transformations most likely involve a [3,5]-sigmatropic rearrangement process. Topics: Aza Compounds; Bridged-Ring Compounds; Cyclopropanes; Diterpenes; Organometallic Compounds; Oxidation-Reduction; Pyridinium Compounds; Quantum Theory	2012
Enantioselective total synthesis of (+)-salvileucalin B. Journal of the American Chemical Society, 2011, Feb-02, Volume: 133, Issue:4 An enantioselective total synthesis of the diterpenoid natural product (+)-salvileucalin B is reported. Key findings include a copper-catalyzed arene cyclopropanation reaction to provide the unusual norcaradiene core and a reversible retro-Claisen rearrangement of a highly functionalized norcaradiene intermediate. Topics: Cyclopropanes; Diterpenes; Stereoisomerism; Substrate Specificity	2011

Article

Year

Reversible cyclopropane ring-cleavage reactions within etheno-bridged [4.3.1]propelladiene frameworks leading to aza- and oxa-[5.6.5.6]fenestratetraenes.

Chemistry (Weinheim an der Bergstrasse, Germany), 2012, Oct-22, Volume: 18, Issue:43

Opening and closing a chemical window: oxidation of the etheno-bridged [4.3.1]propelladienol 1 with pyridinium chlorochromate (PCC) affords oxa[5.6.5.6]fenestratetraene 2. The reduction of 2 with diisobutylaluminum hydride (DIBAl-H) leads to the regeneration of its precursor (1). These transformations most likely involve a [3,5]-sigmatropic rearrangement process.

Topics: Aza Compounds; Bridged-Ring Compounds; Cyclopropanes; Diterpenes; Organometallic Compounds; Oxidation-Reduction; Pyridinium Compounds; Quantum Theory

2012

Enantioselective total synthesis of (+)-salvileucalin B.

Journal of the American Chemical Society, 2011, Feb-02, Volume: 133, Issue:4

An enantioselective total synthesis of the diterpenoid natural product (+)-salvileucalin B is reported. Key findings include a copper-catalyzed arene cyclopropanation reaction to provide the unusual norcaradiene core and a reversible retro-Claisen rearrangement of a highly functionalized norcaradiene intermediate.

Topics: Cyclopropanes; Diterpenes; Stereoisomerism; Substrate Specificity

2011