salicylates has been researched along with sodium-hydride* in 2 studies
2 other study(ies) available for salicylates and sodium-hydride
| Article | Year |
|---|---|
Carboxylation of Phenols with CO2 at Atmospheric Pressure.
A convenient and efficient method for the ortho-carboxylation of phenols under atmospheric CO2 pressure has been developed. This method provides an alternative to the previously reported Kolbe-Schmitt method, which requires very high pressures of CO2 . The addition of a trisubstituted phenol has proved essential for the successful carboxylation of phenols with CO2 at standard atmospheric pressure, allowing the efficient preparation of a broad variety of salicylic acids. Topics: Atmospheric Pressure; Carbon Dioxide; Carboxylic Acids; Cresols; Organic Chemistry Phenomena; Phenols; Salicylates; Sodium Compounds; Temperature | 2016 |
Synthesis of a novel polyhydroxylated salicylic acid lactone framework.
The facile preparation of a novel 8-membered polyhydroxylated salicylic acid lactone from 2,6-dihydroxybenzoic acid and sodium thio-D-glucose is described. The key step involved a sodium hydride promoted intramolecular lactonization in the presence of excess TMSCl, which led to isolation of the "natural product like" lactone. Topics: Catalysis; Glucose; Hydroxybenzoates; Indole Alkaloids; Lactones; Molecular Structure; Salicylates; Sodium Compounds; Stereoisomerism | 2009 |