s-benzyl-phenylmethanethiosulfinate and cumene

s-benzyl-phenylmethanethiosulfinate has been researched along with cumene* in 1 studies

Other Studies

1 other study(ies) available for s-benzyl-phenylmethanethiosulfinate and cumene

ArticleYear
Antioxidant activity of the new thiosulfinate derivative, S-benzyl phenylmethanethiosulfinate, from Petiveria alliacea L.
    Organic & biomolecular chemistry, 2008, Mar-21, Volume: 6, Issue:6

    The antioxidant effects of the new thiosulfinate derivative, S-benzyl phenylmethanethiosulfinate (BPT), against the oxidation of cumene and methyl linoleate (ML) in chlorobenzene were studied in detail using HPLC. The results showed that BPT provided effective inhibition with a well-defined induction period under these oxidation conditions, and it was found that the stoichiometric factor (n), the number of peroxyl radicals trapped by one antioxidant molecule, of BPT is about 2. We then undertook a thorough investigation aimed at elucidating the active structural site of BPT. Various model compounds, such as diphenyl disulfide, dibenzyl disulfide, S-phenyl benzenethiosulfinate and S-ethyl phenylmethanethiosulfinate, were used which provided evidence that the benzylic hydrogen of BPT is mainly associated with the peroxyl radical scavenging. Moreover, we measured the rate constant for the reaction of BPT with peroxyl radicals derived from cumene and ML in chlorobenzene, and based on these measurements, BPT reacts with these peroxyl radicals with a rate constant of k(inh) = 8.6 x 10(3) and 6.2 x 10(4) M(-1) s(-1), respectively.

    Topics: Antioxidants; Benzene Derivatives; Chromatography, High Pressure Liquid; Free Radical Scavengers; Kinetics; Linoleic Acids; Oxidation-Reduction; Phytolaccaceae; Plant Roots; Structure-Activity Relationship; Sulfinic Acids

2008