ripostatin-a has been researched along with 1-3-butadiene* in 1 studies
1 other study(ies) available for ripostatin-a and 1-3-butadiene
Article | Year |
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Palladium-catalyzed 1,4-difunctionalization of butadiene to form skipped polyenes.
A palladium-catalyzed 1,4-addition across the commodity chemical 1,3-butadiene to afford skipped polyene products is reported. Through a palladium σ → π → σ allyl isomerization, two new carbon-carbon bonds are formed with high regioselectivity and trans stereoselectivity of the newly formed alkene. The utility of this method is highlighted by the successful synthesis of the ripostatin A skipped triene core. Topics: Butadienes; Catalysis; DNA-Directed RNA Polymerases; Lactones; Palladium; Polyenes; Stereoisomerism | 2013 |