rifamycin-s and vinyl-acetate

rifamycin-s has been researched along with vinyl-acetate* in 1 studies

Other Studies

1 other study(ies) available for rifamycin-s and vinyl-acetate

Article	Year
Enzymatic desymmetrization of a meso polyol corresponding to the C(19)-C(27) segment of rifamycin S. The Journal of organic chemistry, 2000, Mar-24, Volume: 65, Issue:6 The stereoselective acylation of meso polyol 2 by vinyl acetate (solvent and acyl donor) in the presence of porcine pancreas lipase gave the corresponding monoester 5 in good yield (76%) and high enantiomeric purity (ee > 98%). The enzymatic reaction was also highly regioselective for a primary alcohol end group, and the two unprotected secondary alcohols were not involved. Compound 5 corresponds to the C(19)-C(27) fragment of rifamycin S. Topics: Acylation; Alcohols; Anti-Bacterial Agents; Binding Sites; Burkholderia cepacia; DNA-Directed RNA Polymerases; Fluorine; Gastrointestinal Agents; Magnetic Resonance Spectroscopy; Models, Molecular; Pancrelipase; Pseudomonas fluorescens; Rifamycins; Stereoisomerism; Vinyl Compounds	2000

Article

Year

Enzymatic desymmetrization of a meso polyol corresponding to the C(19)-C(27) segment of rifamycin S.

The Journal of organic chemistry, 2000, Mar-24, Volume: 65, Issue:6

The stereoselective acylation of meso polyol 2 by vinyl acetate (solvent and acyl donor) in the presence of porcine pancreas lipase gave the corresponding monoester 5 in good yield (76%) and high enantiomeric purity (ee > 98%). The enzymatic reaction was also highly regioselective for a primary alcohol end group, and the two unprotected secondary alcohols were not involved. Compound 5 corresponds to the C(19)-C(27) fragment of rifamycin S.

Topics: Acylation; Alcohols; Anti-Bacterial Agents; Binding Sites; Burkholderia cepacia; DNA-Directed RNA Polymerases; Fluorine; Gastrointestinal Agents; Magnetic Resonance Spectroscopy; Models, Molecular; Pancrelipase; Pseudomonas fluorescens; Rifamycins; Stereoisomerism; Vinyl Compounds

2000