rhodinose and colitose

rhodinose has been researched along with colitose* in 1 studies

Other Studies

1 other study(ies) available for rhodinose and colitose

ArticleYear
De novo synthesis of L-colitose and L-rhodinose building blocks.
    The Journal of organic chemistry, 2012, Jan-20, Volume: 77, Issue:2

    A divergent, practical, and efficient de novo synthesis of fully functionalized L-colitose (3,6-dideoxy-L-galactose), 2-epi-colitose (3,6-dideoxy-L-talose), and L-rhodinose (2,3,6-trideoxy-L-galactose) building blocks has been achieved using inexpensive, commercially available (S)-ethyl lactate as the starting material. The routes center around a diastereoselective Cram-chelated allylation that provides a common homoallylic alcohol intermediate. Oxidation of this common intermediate finally resulted in the synthesis of the three monosaccharide building blocks.

    Topics: Chemistry Techniques, Synthetic; Deoxy Sugars; Monosaccharides

2012