pyrimidinones and melamine

pyrimidinones has been researched along with melamine* in 2 studies

Reviews

1 review(s) available for pyrimidinones and melamine

ArticleYear
Routes to Hydrogen Bonding Chain-End Functionalized Polymers.
    Macromolecular rapid communications, 2012, Dec-21, Volume: 33, Issue:24

    The contribution of supramolecular chemistry to polymer science opens new perspectives for the design of polymer materials exhibiting valuable properties and easier processability due to the dynamic nature of non-covalent interactions. Hydrogen bonding polymers can be used as supramolecular units for yielding larger assemblies that possess attractive features, arising from the combination of polymer properties and the responsiveness of hydrogen bonds. The post-polymerization modification of reactive end-groups is the most common procedure for generating such polymers. Examples of polymerizations mediated by hydrogen bonding-functionalized precursors have also recently been reported. This contribution reviews the current synthetic routes toward hydrogen bonding sticker chain-end functionalized polymers.

    Topics: Benzamides; Benzoic Acid; Carboxylic Acids; Hydrogen Bonding; Oligopeptides; Peptidomimetics; Polymerization; Polymers; Pyrimidinones; Triazines; Urea; Urethane

2012

Other Studies

1 other study(ies) available for pyrimidinones and melamine

ArticleYear
Merocyanine dyes containing imide functional groups: synthesis and studies on hydrogen bonding to melamine receptors.
    The Journal of organic chemistry, 2003, Nov-14, Volume: 68, Issue:23

    The condensation of the CH acidic heterocycles 4-alkyl-2,6-dioxo-1,2,5,6-tetrahydropyridine-3-carbonitrile (5a and b) and barbituric acid (15) with electron-rich thiophene aldehydes and benzaldehyde derivatives affords the respective monomethine dyes 10-13 and 17-19. The formylation of 5a,b and 15 with N,N'-diphenylformamidine or dibutylformamide in acetic anhydride and further reaction with 4-picolinium salts 9a,b provide the dimethine dyes 14 and 20a,b. Triple hydrogen bonding of the imide groups of merocyanine dyes 10-14 has been investigated by NMR titration experiments with melamine 21. Despite rather pronounced variations of the charge-transfer properties within the given series of dyes, minor changes of their binding constants have been observed. These results could be rationalized by semiempirical calculations that reveal small changes in the charge density at the oxygen functionalities involved in hydrogen bonding upon variation of the electron-donating carbocyclic or heterocyclic groups at the terminal double bond. Although the binding constants for triple hydrogen bonding between imides and melamines are rather weak in chloroform, they proved to be strong enough to facilitate dissolution of some of these dyes in aliphatic solvents by coordination to amphiphilic melamines and dipolar aggregation. UV-vis spectral changes observed in methylcyclohexane vs chloroform suggest the formation of colloidal assemblies through noncovalent polymerization.

    Topics: Hydrogen Bonding; Magnetic Resonance Spectroscopy; Pyrimidinones; Triazines

2003