propargylamine has been researched along with 12-oxophytodienoic-acid* in 1 studies
1 other study(ies) available for propargylamine and 12-oxophytodienoic-acid
Article | Year |
---|---|
Pauson-Khand adducts of N-Boc-propargylamine: a new approach to 4,5-disubstituted cyclopentenones.
A new approach to the synthesis of 4,5-disubstituted cyclopentenones is described. The strategy is based on the Pauson-Khand (PK) reaction of norbornadiene and N-Boc-propargylamine as an alkyne with a masked leaving group, which can be eliminated at will. This approach to the synthesis of 4,5-disubstituted cyclopentenones overcomes the problem of using the alkylation to introduce the α side chain. As an example, prostane 13-epi-12-oxo-phytodienoic acid (13-epi-12-oxo-PDA) methyl ester was synthesized. Topics: Alkylation; Cyclopentanes; Fatty Acids, Unsaturated; Molecular Structure; Pargyline; Propylamines; Stereoisomerism | 2013 |